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Preparation of Complexes Bearing N‐Alkylated, Anionic or Protic CAACs Through Oxidative Addition of 2‐Halogenoindole Derivatives
CAAC precursors 2‐chloro‐3,3‐dimethylindole 1 and 2‐chloro‐1‐ethyl‐3,3‐dimethylindolium tetrafluoroborate 2BF(4) have been prepared and oxidatively added to [M(PPh(3))(4)] (M=Pd, Pt). Salt 2BF(4) reacts with [Pd(PPh(3))(4)] in toluene at 25 °C over 4 days to yield complex cis‐[3]BF(4) featuring an N...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898591/ https://www.ncbi.nlm.nih.gov/pubmed/33022849 http://dx.doi.org/10.1002/anie.202010988 |