Cargando…
Isolation of a 16π‐Electrons 1,4‐Diphosphinine‐1,4‐diide with a Planar C(4)P(2) Ring
Herein, we report the first 1,4‐diphosphinine‐1,4‐diide compound [(ADC(Ph))P](2) (5‐Ph) (ADC(Ph)=PhC{(NDipp)C}(2); Dipp=2,6‐iPr(2)C(6)H(3)) derived from an anionic dicarbene (ADC(Ph)) as a red crystalline solid. Compound 5‐Ph containing a 16π‐electron planar fused‐tricyclic ring system was obtained...
| Autores principales: | , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898681/ https://www.ncbi.nlm.nih.gov/pubmed/33080114 http://dx.doi.org/10.1002/chem.202003617 |