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Not‐So‐Innocent Anions Determine the Mechanism of Cationic Alkylators

Alkylating reagents based on thioimidazolium ionic liquids were synthesized and the influence of the anion on the alkylation reaction mechanism explored in detail using both experimental and computational methods. Thioimidazolium cations transfer alkyl substituents to nucleophiles, however the react...

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Detalles Bibliográficos
Autores principales:	Taimoory, S. Maryamdokht, Cataldo, Vincenzo Alessandro, Schäfer, Andreas, Trant, John F., Guterman, Ryan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898791/ https://www.ncbi.nlm.nih.gov/pubmed/33137244 http://dx.doi.org/10.1002/chem.202004208

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