Photochemistry with Chlorine Trifluoride: Syntheses and Characterization of Difluorooxychloronium(V) Hexafluorido(non)metallates(V), [ClOF(2)][MF(6)] (M=V, Nb, Ta, Ru, Os, Ir, P, Sb)

A photochemical route to salts consisting of difluorooxychloronium(V) cations, [ClOF(2)](+), and hexafluorido(non)metallate(V) anions, [MF(6)](−) (M=V, Nb, Ta, Ru, Os, Ir, P, Sb) is presented. As starting materials, either metals, oxygen and ClF(3) or oxides and ClF(3) are used. The prepared compoun...

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Detalles Bibliográficos
Autores principales: Scheibe, Benjamin, Karttunen, Antti J., Weigend, Florian, Kraus, Florian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
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Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898883/
https://www.ncbi.nlm.nih.gov/pubmed/32897578
http://dx.doi.org/10.1002/chem.202003629

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