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Reaction Mechanism of Pd‐Catalyzed “CO‐Free” Carbonylation Reaction Uncovered by In Situ Spectroscopy: The Formyl Mechanism

“CO‐free” carbonylation reactions, where synthesis gas (CO/H(2)) is substituted by C1 surrogate molecules like formaldehyde or formic acid, have received widespread attention in homogeneous catalysis lately. Although a broad range of organics is available via this method, still relatively little is...

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Detalles Bibliográficos
Autores principales: Geitner, Robert, Gurinov, Andrei, Huang, Tianbai, Kupfer, Stephan, Gräfe, Stefanie, Weckhuysen, Bert M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898928/
https://www.ncbi.nlm.nih.gov/pubmed/33150717
http://dx.doi.org/10.1002/anie.202011152