How Lewis Acids Catalyze Ring-Openings of Cyclohexene Oxide

[Image: see text] We have quantum chemically studied the Lewis acid-catalyzed epoxide ring-opening reaction of cyclohexene epoxide by MeZH (Z = O, S, and NH) using relativistic dispersion-corrected density functional theory. We found that the reaction barrier of the Lewis acid-catalyzed epoxide ring...

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Detalles Bibliográficos
Autores principales: Hansen, Thomas, Vermeeren, Pascal, Yoshisada, Ryoji, Filippov, Dmitri V., van der Marel, Gijsbert A., Codée, Jeroen D. C., Hamlin, Trevor A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7901664/
https://www.ncbi.nlm.nih.gov/pubmed/33538169
http://dx.doi.org/10.1021/acs.joc.0c02955

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