Cargando…

Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations

We illustrate how, contrary to common belief, transient Fluctuation Relations (FRs) for systems in constant external magnetic field hold without the inversion of the field. Building on previous work providing generalized time-reversal symmetries for systems in parallel external magnetic and electric...

Descripción completa

Detalles Bibliográficos
Autores principales: Coretti, Alessandro, Rondoni, Lamberto, Bonella, Sara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7911387/
https://www.ncbi.nlm.nih.gov/pubmed/33504011
http://dx.doi.org/10.3390/e23020146
_version_ 1783656329535029248
author Coretti, Alessandro
Rondoni, Lamberto
Bonella, Sara
author_facet Coretti, Alessandro
Rondoni, Lamberto
Bonella, Sara
author_sort Coretti, Alessandro
collection PubMed
description We illustrate how, contrary to common belief, transient Fluctuation Relations (FRs) for systems in constant external magnetic field hold without the inversion of the field. Building on previous work providing generalized time-reversal symmetries for systems in parallel external magnetic and electric fields, we observe that the standard proof of these important nonequilibrium properties can be fully reinstated in the presence of net dissipation. This generalizes recent results for the FRs in orthogonal fields—an interesting but less commonly investigated geometry—and enables direct comparison with existing literature. We also present for the first time a numerical demonstration of the validity of the transient FRs with nonzero magnetic field via nonequilibrium molecular dynamics simulations of a realistic model of liquid NaCl.
format Online
Article
Text
id pubmed-7911387
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-79113872021-02-28 Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations Coretti, Alessandro Rondoni, Lamberto Bonella, Sara Entropy (Basel) Article We illustrate how, contrary to common belief, transient Fluctuation Relations (FRs) for systems in constant external magnetic field hold without the inversion of the field. Building on previous work providing generalized time-reversal symmetries for systems in parallel external magnetic and electric fields, we observe that the standard proof of these important nonequilibrium properties can be fully reinstated in the presence of net dissipation. This generalizes recent results for the FRs in orthogonal fields—an interesting but less commonly investigated geometry—and enables direct comparison with existing literature. We also present for the first time a numerical demonstration of the validity of the transient FRs with nonzero magnetic field via nonequilibrium molecular dynamics simulations of a realistic model of liquid NaCl. MDPI 2021-01-25 /pmc/articles/PMC7911387/ /pubmed/33504011 http://dx.doi.org/10.3390/e23020146 Text en © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Coretti, Alessandro
Rondoni, Lamberto
Bonella, Sara
Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations
title Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations
title_full Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations
title_fullStr Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations
title_full_unstemmed Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations
title_short Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations
title_sort fluctuation relations for dissipative systems in constant external magnetic field: theory and molecular dynamics simulations
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7911387/
https://www.ncbi.nlm.nih.gov/pubmed/33504011
http://dx.doi.org/10.3390/e23020146
work_keys_str_mv AT corettialessandro fluctuationrelationsfordissipativesystemsinconstantexternalmagneticfieldtheoryandmoleculardynamicssimulations
AT rondonilamberto fluctuationrelationsfordissipativesystemsinconstantexternalmagneticfieldtheoryandmoleculardynamicssimulations
AT bonellasara fluctuationrelationsfordissipativesystemsinconstantexternalmagneticfieldtheoryandmoleculardynamicssimulations