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Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations
We illustrate how, contrary to common belief, transient Fluctuation Relations (FRs) for systems in constant external magnetic field hold without the inversion of the field. Building on previous work providing generalized time-reversal symmetries for systems in parallel external magnetic and electric...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7911387/ https://www.ncbi.nlm.nih.gov/pubmed/33504011 http://dx.doi.org/10.3390/e23020146 |
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author | Coretti, Alessandro Rondoni, Lamberto Bonella, Sara |
author_facet | Coretti, Alessandro Rondoni, Lamberto Bonella, Sara |
author_sort | Coretti, Alessandro |
collection | PubMed |
description | We illustrate how, contrary to common belief, transient Fluctuation Relations (FRs) for systems in constant external magnetic field hold without the inversion of the field. Building on previous work providing generalized time-reversal symmetries for systems in parallel external magnetic and electric fields, we observe that the standard proof of these important nonequilibrium properties can be fully reinstated in the presence of net dissipation. This generalizes recent results for the FRs in orthogonal fields—an interesting but less commonly investigated geometry—and enables direct comparison with existing literature. We also present for the first time a numerical demonstration of the validity of the transient FRs with nonzero magnetic field via nonequilibrium molecular dynamics simulations of a realistic model of liquid NaCl. |
format | Online Article Text |
id | pubmed-7911387 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-79113872021-02-28 Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations Coretti, Alessandro Rondoni, Lamberto Bonella, Sara Entropy (Basel) Article We illustrate how, contrary to common belief, transient Fluctuation Relations (FRs) for systems in constant external magnetic field hold without the inversion of the field. Building on previous work providing generalized time-reversal symmetries for systems in parallel external magnetic and electric fields, we observe that the standard proof of these important nonequilibrium properties can be fully reinstated in the presence of net dissipation. This generalizes recent results for the FRs in orthogonal fields—an interesting but less commonly investigated geometry—and enables direct comparison with existing literature. We also present for the first time a numerical demonstration of the validity of the transient FRs with nonzero magnetic field via nonequilibrium molecular dynamics simulations of a realistic model of liquid NaCl. MDPI 2021-01-25 /pmc/articles/PMC7911387/ /pubmed/33504011 http://dx.doi.org/10.3390/e23020146 Text en © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Coretti, Alessandro Rondoni, Lamberto Bonella, Sara Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations |
title | Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations |
title_full | Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations |
title_fullStr | Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations |
title_full_unstemmed | Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations |
title_short | Fluctuation Relations for Dissipative Systems in Constant External Magnetic Field: Theory and Molecular Dynamics Simulations |
title_sort | fluctuation relations for dissipative systems in constant external magnetic field: theory and molecular dynamics simulations |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7911387/ https://www.ncbi.nlm.nih.gov/pubmed/33504011 http://dx.doi.org/10.3390/e23020146 |
work_keys_str_mv | AT corettialessandro fluctuationrelationsfordissipativesystemsinconstantexternalmagneticfieldtheoryandmoleculardynamicssimulations AT rondonilamberto fluctuationrelationsfordissipativesystemsinconstantexternalmagneticfieldtheoryandmoleculardynamicssimulations AT bonellasara fluctuationrelationsfordissipativesystemsinconstantexternalmagneticfieldtheoryandmoleculardynamicssimulations |