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Comparative Study on Toughening Effect of PTS and PTK in Various Epoxy Resins
This study investigated the toughening effect of in situ polytriazoleketone (PTK) and polytriazolesulfone (PTS) toughening agent when applied to various epoxy resins, such as diglycidyl ether of bisphenol A (DGEBA), diglycidyl ether of bisphenol F (DGEBF), and triglycidyl p-aminophenol (TGAP) with 3...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7916120/ https://www.ncbi.nlm.nih.gov/pubmed/33572307 http://dx.doi.org/10.3390/polym13040518 |
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author | Kwon, Woong Han, Minwoo Kim, Jongwon Jeong, Euigyung |
author_facet | Kwon, Woong Han, Minwoo Kim, Jongwon Jeong, Euigyung |
author_sort | Kwon, Woong |
collection | PubMed |
description | This study investigated the toughening effect of in situ polytriazoleketone (PTK) and polytriazolesulfone (PTS) toughening agent when applied to various epoxy resins, such as diglycidyl ether of bisphenol A (DGEBA), diglycidyl ether of bisphenol F (DGEBF), and triglycidyl p-aminophenol (TGAP) with 3,3′-diaminodiphenylsulfone as a curing agent. The fracture toughness, tensile properties, and thermal properties of the prepared epoxy samples were evaluated and compared. When PTK was mixed with DGEBF, the fracture toughness was improved by 27% with 8.6% increased tensile strength compared to the untoughened DGEBF. When PTS was mixed with TGAP, the fracture toughness was improved by 51% without decreasing tensile properties compared to the untoughened TGAP. However, when PTK or PTS was mixed with other epoxy resins, the fracture toughness decreased or improved with decreasing tensile properties. This is attributed to the poor miscibility between the solid-state monomer of PTK (4,4′-bis(propynyloxy)benzophenone (PBP)) or PTS (4,4′-sulfonylbis(propynyloxy)benzene (SPB)) and the epoxy resin, resulting in the polymerization of low molecular weight PTK or PTS in epoxy resin. Therefore, the toughening effect of PTK or PTS can be maximized by the appropriate selection of epoxy resin based on the miscibility between PBP or SPB and the resin. |
format | Online Article Text |
id | pubmed-7916120 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-79161202021-03-01 Comparative Study on Toughening Effect of PTS and PTK in Various Epoxy Resins Kwon, Woong Han, Minwoo Kim, Jongwon Jeong, Euigyung Polymers (Basel) Article This study investigated the toughening effect of in situ polytriazoleketone (PTK) and polytriazolesulfone (PTS) toughening agent when applied to various epoxy resins, such as diglycidyl ether of bisphenol A (DGEBA), diglycidyl ether of bisphenol F (DGEBF), and triglycidyl p-aminophenol (TGAP) with 3,3′-diaminodiphenylsulfone as a curing agent. The fracture toughness, tensile properties, and thermal properties of the prepared epoxy samples were evaluated and compared. When PTK was mixed with DGEBF, the fracture toughness was improved by 27% with 8.6% increased tensile strength compared to the untoughened DGEBF. When PTS was mixed with TGAP, the fracture toughness was improved by 51% without decreasing tensile properties compared to the untoughened TGAP. However, when PTK or PTS was mixed with other epoxy resins, the fracture toughness decreased or improved with decreasing tensile properties. This is attributed to the poor miscibility between the solid-state monomer of PTK (4,4′-bis(propynyloxy)benzophenone (PBP)) or PTS (4,4′-sulfonylbis(propynyloxy)benzene (SPB)) and the epoxy resin, resulting in the polymerization of low molecular weight PTK or PTS in epoxy resin. Therefore, the toughening effect of PTK or PTS can be maximized by the appropriate selection of epoxy resin based on the miscibility between PBP or SPB and the resin. MDPI 2021-02-09 /pmc/articles/PMC7916120/ /pubmed/33572307 http://dx.doi.org/10.3390/polym13040518 Text en © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Kwon, Woong Han, Minwoo Kim, Jongwon Jeong, Euigyung Comparative Study on Toughening Effect of PTS and PTK in Various Epoxy Resins |
title | Comparative Study on Toughening Effect of PTS and PTK in Various Epoxy Resins |
title_full | Comparative Study on Toughening Effect of PTS and PTK in Various Epoxy Resins |
title_fullStr | Comparative Study on Toughening Effect of PTS and PTK in Various Epoxy Resins |
title_full_unstemmed | Comparative Study on Toughening Effect of PTS and PTK in Various Epoxy Resins |
title_short | Comparative Study on Toughening Effect of PTS and PTK in Various Epoxy Resins |
title_sort | comparative study on toughening effect of pts and ptk in various epoxy resins |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7916120/ https://www.ncbi.nlm.nih.gov/pubmed/33572307 http://dx.doi.org/10.3390/polym13040518 |
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