Versatile Reactivity of Mn(II) Complexes in Reactions with N-Donor Heterocycles: Metamorphosis of Labile Homometallic Pivalates vs. Assembling of Endurable Heterometallic Acetates

Reaction of 2,2′-bipyridine (2,2′-bipy) or 1,10-phenantroline (phen) with [Mn(Piv)(2)(EtOH)](n) led to the formation of binuclear complexes [Mn(2)(Piv)(4)L(2)] (L = 2,2′-bipy (1), phen (2); Piv(−) is the anion of pivalic acid). Oxidation of 1 or 2 by air oxygen resulted in the formation of tetranucl...

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Detalles Bibliográficos
Autores principales: Polunin, Ruslan A., Evstifeev, Igor S., Cador, Olivier, Golhen, Stéphane, Gavrilenko, Konstantin S., Lytvynenko, Anton S., Efimov, Nikolay N., Minin, Vadim V., Bogomyakov, Artem S., Ouahab, Lahcène, Kolotilov, Sergey V., Kiskin, Mikhail A., Eremenko, Igor L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7919295/
https://www.ncbi.nlm.nih.gov/pubmed/33672016
http://dx.doi.org/10.3390/molecules26041021

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