Electrochemical Performance Enhancement of Micro-Sized Porous Si by Integrating with Nano-Sn and Carbonaceous Materials

Silicon is investigated as one of the most prospective anode materials for next generation lithium ion batteries due to its superior theoretical capacity (3580 mAh g(−1)), but its commercial application is hindered by its inferior dynamic property and poor cyclic performance. Herein, we presented a facile method for preparing silicon/tin@graphite-amorphous carbon (Si/Sn@G–C) composite through hydrolyzing of SnCl(2) on etched Fe–Si alloys, followed by ball milling mixture and carbon pyrolysis reduction processes. Structural characterization indicates that the nano-Sn decorated porous Si particles are coated by graphite and amorphous carbon. The addition of nano-Sn and carbonaceous materials can effectively improve the dynamic performance and the structure stability of the composite. As a result, it exhibits an initial columbic efficiency of 79% and a stable specific capacity of 825.5 mAh g(−1) after 300 cycles at a current density of 1 A g(−1). Besides, the Si/Sn@G–C composite exerts enhanced rate performance with 445 mAh g(−1) retention at 5 A g(−1). This work provides an approach to improve the electrochemical performance of Si anode materials through reasonable compositing with elements from the same family.