Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles

The controlled assembly of well‐defined planar nanoclusters from molecular precursors is synthetically challenging and often plagued by the predominant formation of 3D‐structures and nanoparticles. Herein, we report planar iron hydride nanoclusters from reactions of main group element hydrides with...

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Detalles Bibliográficos
Autores principales: Chakraborty, Uttam, Bügel, Patrick, Fritsch, Lorena, Weigend, Florian, Bauer, Matthias, Jacobi von Wangelin, Axel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7919527/
https://www.ncbi.nlm.nih.gov/pubmed/33646644
http://dx.doi.org/10.1002/open.202000307
Descripción
Sumario:The controlled assembly of well‐defined planar nanoclusters from molecular precursors is synthetically challenging and often plagued by the predominant formation of 3D‐structures and nanoparticles. Herein, we report planar iron hydride nanoclusters from reactions of main group element hydrides with iron(II) bis(hexamethyldisilazide). The structures and properties of isolated Fe(4), Fe(6), and Fe(7) nanoplatelets and calculated intermediates enable an unprecedented insight into the underlying building principle and growth mechanism of iron clusters, metal monolayers, and nanoparticles.

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