Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles

The controlled assembly of well‐defined planar nanoclusters from molecular precursors is synthetically challenging and often plagued by the predominant formation of 3D‐structures and nanoparticles. Herein, we report planar iron hydride nanoclusters from reactions of main group element hydrides with...

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Detalles Bibliográficos
Autores principales: Chakraborty, Uttam, Bügel, Patrick, Fritsch, Lorena, Weigend, Florian, Bauer, Matthias, Jacobi von Wangelin, Axel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7919527/
https://www.ncbi.nlm.nih.gov/pubmed/33646644
http://dx.doi.org/10.1002/open.202000307
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author Chakraborty, Uttam
Bügel, Patrick
Fritsch, Lorena
Weigend, Florian
Bauer, Matthias
Jacobi von Wangelin, Axel
author_facet Chakraborty, Uttam
Bügel, Patrick
Fritsch, Lorena
Weigend, Florian
Bauer, Matthias
Jacobi von Wangelin, Axel
author_sort Chakraborty, Uttam
collection PubMed
description The controlled assembly of well‐defined planar nanoclusters from molecular precursors is synthetically challenging and often plagued by the predominant formation of 3D‐structures and nanoparticles. Herein, we report planar iron hydride nanoclusters from reactions of main group element hydrides with iron(II) bis(hexamethyldisilazide). The structures and properties of isolated Fe(4), Fe(6), and Fe(7) nanoplatelets and calculated intermediates enable an unprecedented insight into the underlying building principle and growth mechanism of iron clusters, metal monolayers, and nanoparticles.
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spelling pubmed-79195272021-03-05 Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles Chakraborty, Uttam Bügel, Patrick Fritsch, Lorena Weigend, Florian Bauer, Matthias Jacobi von Wangelin, Axel ChemistryOpen Communications The controlled assembly of well‐defined planar nanoclusters from molecular precursors is synthetically challenging and often plagued by the predominant formation of 3D‐structures and nanoparticles. Herein, we report planar iron hydride nanoclusters from reactions of main group element hydrides with iron(II) bis(hexamethyldisilazide). The structures and properties of isolated Fe(4), Fe(6), and Fe(7) nanoplatelets and calculated intermediates enable an unprecedented insight into the underlying building principle and growth mechanism of iron clusters, metal monolayers, and nanoparticles. John Wiley and Sons Inc. 2021-03-01 /pmc/articles/PMC7919527/ /pubmed/33646644 http://dx.doi.org/10.1002/open.202000307 Text en © 2021 The Authors. Published by Wiley-VCH GmbH This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Chakraborty, Uttam
Bügel, Patrick
Fritsch, Lorena
Weigend, Florian
Bauer, Matthias
Jacobi von Wangelin, Axel
Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles
title Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles
title_full Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles
title_fullStr Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles
title_full_unstemmed Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles
title_short Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles
title_sort planar iron hydride nanoclusters: combined spectroscopic and theoretical insights into structures and building principles
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7919527/
https://www.ncbi.nlm.nih.gov/pubmed/33646644
http://dx.doi.org/10.1002/open.202000307
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