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Cusp of Non-Gaussian Density of Particles for a Diffusing Diffusivity Model

We study a two state “jumping diffusivity” model for a Brownian process alternating between two different diffusion constants, [Formula: see text] , with random waiting times in both states whose distribution is rather general. In the limit of long measurement times, Gaussian behavior with an effect...

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Autores principales: Hidalgo-Soria, M., Barkai, E., Burov, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7922965/
https://www.ncbi.nlm.nih.gov/pubmed/33671127
http://dx.doi.org/10.3390/e23020231
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author Hidalgo-Soria, M.
Barkai, E.
Burov, S.
author_facet Hidalgo-Soria, M.
Barkai, E.
Burov, S.
author_sort Hidalgo-Soria, M.
collection PubMed
description We study a two state “jumping diffusivity” model for a Brownian process alternating between two different diffusion constants, [Formula: see text] , with random waiting times in both states whose distribution is rather general. In the limit of long measurement times, Gaussian behavior with an effective diffusion coefficient is recovered. We show that, for equilibrium initial conditions and when the limit of the diffusion coefficient [Formula: see text] is taken, the short time behavior leads to a cusp, namely a non-analytical behavior, in the distribution of the displacements [Formula: see text] for [Formula: see text]. Visually this cusp, or tent-like shape, resembles similar behavior found in many experiments of diffusing particles in disordered environments, such as glassy systems and intracellular media. This general result depends only on the existence of finite mean values of the waiting times at the different states of the model. Gaussian statistics in the long time limit is achieved due to ergodicity and convergence of the distribution of the temporal occupation fraction in state [Formula: see text] to a [Formula: see text]-function. The short time behavior of the same quantity converges to a uniform distribution, which leads to the non-analyticity in [Formula: see text]. We demonstrate how super-statistical framework is a zeroth order short time expansion of [Formula: see text] , in the number of transitions, that does not yield the cusp like shape. The latter, considered as the key feature of experiments in the field, is found with the first correction in perturbation theory.
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spelling pubmed-79229652021-03-03 Cusp of Non-Gaussian Density of Particles for a Diffusing Diffusivity Model Hidalgo-Soria, M. Barkai, E. Burov, S. Entropy (Basel) Article We study a two state “jumping diffusivity” model for a Brownian process alternating between two different diffusion constants, [Formula: see text] , with random waiting times in both states whose distribution is rather general. In the limit of long measurement times, Gaussian behavior with an effective diffusion coefficient is recovered. We show that, for equilibrium initial conditions and when the limit of the diffusion coefficient [Formula: see text] is taken, the short time behavior leads to a cusp, namely a non-analytical behavior, in the distribution of the displacements [Formula: see text] for [Formula: see text]. Visually this cusp, or tent-like shape, resembles similar behavior found in many experiments of diffusing particles in disordered environments, such as glassy systems and intracellular media. This general result depends only on the existence of finite mean values of the waiting times at the different states of the model. Gaussian statistics in the long time limit is achieved due to ergodicity and convergence of the distribution of the temporal occupation fraction in state [Formula: see text] to a [Formula: see text]-function. The short time behavior of the same quantity converges to a uniform distribution, which leads to the non-analyticity in [Formula: see text]. We demonstrate how super-statistical framework is a zeroth order short time expansion of [Formula: see text] , in the number of transitions, that does not yield the cusp like shape. The latter, considered as the key feature of experiments in the field, is found with the first correction in perturbation theory. MDPI 2021-02-17 /pmc/articles/PMC7922965/ /pubmed/33671127 http://dx.doi.org/10.3390/e23020231 Text en © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Hidalgo-Soria, M.
Barkai, E.
Burov, S.
Cusp of Non-Gaussian Density of Particles for a Diffusing Diffusivity Model
title Cusp of Non-Gaussian Density of Particles for a Diffusing Diffusivity Model
title_full Cusp of Non-Gaussian Density of Particles for a Diffusing Diffusivity Model
title_fullStr Cusp of Non-Gaussian Density of Particles for a Diffusing Diffusivity Model
title_full_unstemmed Cusp of Non-Gaussian Density of Particles for a Diffusing Diffusivity Model
title_short Cusp of Non-Gaussian Density of Particles for a Diffusing Diffusivity Model
title_sort cusp of non-gaussian density of particles for a diffusing diffusivity model
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7922965/
https://www.ncbi.nlm.nih.gov/pubmed/33671127
http://dx.doi.org/10.3390/e23020231
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