Cargando…
Electrochemical Activity of Lignin Based Composite Membranes
Our society’s most pressing challenges, like high CO(2) emission and the constant battle against energy poverty, require a clean and easier solution to store and utilize the renewable energy resources. However, recent electrochemical components are expensive and harmful to the environment, which res...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7926618/ https://www.ncbi.nlm.nih.gov/pubmed/33670084 http://dx.doi.org/10.3390/polym13040643 |
_version_ | 1783659502585774080 |
---|---|
author | Baloch, Marya Alberro, Mikel Labidi, Jalel |
author_facet | Baloch, Marya Alberro, Mikel Labidi, Jalel |
author_sort | Baloch, Marya |
collection | PubMed |
description | Our society’s most pressing challenges, like high CO(2) emission and the constant battle against energy poverty, require a clean and easier solution to store and utilize the renewable energy resources. However, recent electrochemical components are expensive and harmful to the environment, which restricts their widespread deployment. This study proposes an easy method to synthesize and fabricate composite membranes with abundantly found biomass lignin polymer to replace conventional costly and toxic electrode materials. Easier manipulation of lignin within the polymeric matrix could provide the improved composite to enhance its electrochemical activity. Our major focus is to activate the quinone moiety via oxidation in the polymeric mixture using a strong ionic acid. The physico-chemical and electrochemical characterizations of two different lignins within varied polymeric mixture compositions have been carried out to confirm that the redox properties of pure unmodified lignin could be achieved via intrinsic mutual sharing of the structural properties and intercross linkage leading to improved integrity and redox activity/conductivity. |
format | Online Article Text |
id | pubmed-7926618 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-79266182021-03-04 Electrochemical Activity of Lignin Based Composite Membranes Baloch, Marya Alberro, Mikel Labidi, Jalel Polymers (Basel) Article Our society’s most pressing challenges, like high CO(2) emission and the constant battle against energy poverty, require a clean and easier solution to store and utilize the renewable energy resources. However, recent electrochemical components are expensive and harmful to the environment, which restricts their widespread deployment. This study proposes an easy method to synthesize and fabricate composite membranes with abundantly found biomass lignin polymer to replace conventional costly and toxic electrode materials. Easier manipulation of lignin within the polymeric matrix could provide the improved composite to enhance its electrochemical activity. Our major focus is to activate the quinone moiety via oxidation in the polymeric mixture using a strong ionic acid. The physico-chemical and electrochemical characterizations of two different lignins within varied polymeric mixture compositions have been carried out to confirm that the redox properties of pure unmodified lignin could be achieved via intrinsic mutual sharing of the structural properties and intercross linkage leading to improved integrity and redox activity/conductivity. MDPI 2021-02-21 /pmc/articles/PMC7926618/ /pubmed/33670084 http://dx.doi.org/10.3390/polym13040643 Text en © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Baloch, Marya Alberro, Mikel Labidi, Jalel Electrochemical Activity of Lignin Based Composite Membranes |
title | Electrochemical Activity of Lignin Based Composite Membranes |
title_full | Electrochemical Activity of Lignin Based Composite Membranes |
title_fullStr | Electrochemical Activity of Lignin Based Composite Membranes |
title_full_unstemmed | Electrochemical Activity of Lignin Based Composite Membranes |
title_short | Electrochemical Activity of Lignin Based Composite Membranes |
title_sort | electrochemical activity of lignin based composite membranes |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7926618/ https://www.ncbi.nlm.nih.gov/pubmed/33670084 http://dx.doi.org/10.3390/polym13040643 |
work_keys_str_mv | AT balochmarya electrochemicalactivityofligninbasedcompositemembranes AT alberromikel electrochemicalactivityofligninbasedcompositemembranes AT labidijalel electrochemicalactivityofligninbasedcompositemembranes |