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Electrochemical Activity of Lignin Based Composite Membranes

Our society’s most pressing challenges, like high CO(2) emission and the constant battle against energy poverty, require a clean and easier solution to store and utilize the renewable energy resources. However, recent electrochemical components are expensive and harmful to the environment, which res...

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Detalles Bibliográficos
Autores principales: Baloch, Marya, Alberro, Mikel, Labidi, Jalel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7926618/
https://www.ncbi.nlm.nih.gov/pubmed/33670084
http://dx.doi.org/10.3390/polym13040643
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author Baloch, Marya
Alberro, Mikel
Labidi, Jalel
author_facet Baloch, Marya
Alberro, Mikel
Labidi, Jalel
author_sort Baloch, Marya
collection PubMed
description Our society’s most pressing challenges, like high CO(2) emission and the constant battle against energy poverty, require a clean and easier solution to store and utilize the renewable energy resources. However, recent electrochemical components are expensive and harmful to the environment, which restricts their widespread deployment. This study proposes an easy method to synthesize and fabricate composite membranes with abundantly found biomass lignin polymer to replace conventional costly and toxic electrode materials. Easier manipulation of lignin within the polymeric matrix could provide the improved composite to enhance its electrochemical activity. Our major focus is to activate the quinone moiety via oxidation in the polymeric mixture using a strong ionic acid. The physico-chemical and electrochemical characterizations of two different lignins within varied polymeric mixture compositions have been carried out to confirm that the redox properties of pure unmodified lignin could be achieved via intrinsic mutual sharing of the structural properties and intercross linkage leading to improved integrity and redox activity/conductivity.
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spelling pubmed-79266182021-03-04 Electrochemical Activity of Lignin Based Composite Membranes Baloch, Marya Alberro, Mikel Labidi, Jalel Polymers (Basel) Article Our society’s most pressing challenges, like high CO(2) emission and the constant battle against energy poverty, require a clean and easier solution to store and utilize the renewable energy resources. However, recent electrochemical components are expensive and harmful to the environment, which restricts their widespread deployment. This study proposes an easy method to synthesize and fabricate composite membranes with abundantly found biomass lignin polymer to replace conventional costly and toxic electrode materials. Easier manipulation of lignin within the polymeric matrix could provide the improved composite to enhance its electrochemical activity. Our major focus is to activate the quinone moiety via oxidation in the polymeric mixture using a strong ionic acid. The physico-chemical and electrochemical characterizations of two different lignins within varied polymeric mixture compositions have been carried out to confirm that the redox properties of pure unmodified lignin could be achieved via intrinsic mutual sharing of the structural properties and intercross linkage leading to improved integrity and redox activity/conductivity. MDPI 2021-02-21 /pmc/articles/PMC7926618/ /pubmed/33670084 http://dx.doi.org/10.3390/polym13040643 Text en © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Baloch, Marya
Alberro, Mikel
Labidi, Jalel
Electrochemical Activity of Lignin Based Composite Membranes
title Electrochemical Activity of Lignin Based Composite Membranes
title_full Electrochemical Activity of Lignin Based Composite Membranes
title_fullStr Electrochemical Activity of Lignin Based Composite Membranes
title_full_unstemmed Electrochemical Activity of Lignin Based Composite Membranes
title_short Electrochemical Activity of Lignin Based Composite Membranes
title_sort electrochemical activity of lignin based composite membranes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7926618/
https://www.ncbi.nlm.nih.gov/pubmed/33670084
http://dx.doi.org/10.3390/polym13040643
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