A 3D Silverton-Type Polyoxomolybdate Based on {PrMo(12)O(42)}: Synthesis, Structure, Photoluminescence and Magnetic Properties

A three-dimensional (3D) Silverton-type polyoxomolybdate (POMo) with the formula of NH(4){Mn(4)[PrMo(12)O(42)]}·18H(2)O (1) was successfully isolated and well characterized by single crystal X-ray diffraction, X-ray powder diffraction pattern, infrared spectrum, thermogravimetric and elemental analy...

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Autores principales: Zhao, Yanxin, Sun, Xiaopeng, Ji, Yanfang, Kong, Hui, Chen, Shumin, Ma, Pengtao, Niu, Jingyang, Wang, Jingping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7935544/
https://www.ncbi.nlm.nih.gov/pubmed/33681143
http://dx.doi.org/10.3389/fchem.2021.615595
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author Zhao, Yanxin
Sun, Xiaopeng
Ji, Yanfang
Kong, Hui
Chen, Shumin
Ma, Pengtao
Niu, Jingyang
Wang, Jingping
author_facet Zhao, Yanxin
Sun, Xiaopeng
Ji, Yanfang
Kong, Hui
Chen, Shumin
Ma, Pengtao
Niu, Jingyang
Wang, Jingping
author_sort Zhao, Yanxin
collection PubMed
description A three-dimensional (3D) Silverton-type polyoxomolybdate (POMo) with the formula of NH(4){Mn(4)[PrMo(12)O(42)]}·18H(2)O (1) was successfully isolated and well characterized by single crystal X-ray diffraction, X-ray powder diffraction pattern, infrared spectrum, thermogravimetric and elemental analyses. The inorganic building block {PrMo(12)O(42)} has formed 3D frameworks via the {MnO(6)} linker. The excitation of compound 1 in solid state at 375 nm displays red emission. Moreover, variable temperature magnetic susceptibility measurements indicate that the magnetic behavior in compound 1 is dominated by antiferromagnetic interactions.
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spelling pubmed-79355442021-03-06 A 3D Silverton-Type Polyoxomolybdate Based on {PrMo(12)O(42)}: Synthesis, Structure, Photoluminescence and Magnetic Properties Zhao, Yanxin Sun, Xiaopeng Ji, Yanfang Kong, Hui Chen, Shumin Ma, Pengtao Niu, Jingyang Wang, Jingping Front Chem Chemistry A three-dimensional (3D) Silverton-type polyoxomolybdate (POMo) with the formula of NH(4){Mn(4)[PrMo(12)O(42)]}·18H(2)O (1) was successfully isolated and well characterized by single crystal X-ray diffraction, X-ray powder diffraction pattern, infrared spectrum, thermogravimetric and elemental analyses. The inorganic building block {PrMo(12)O(42)} has formed 3D frameworks via the {MnO(6)} linker. The excitation of compound 1 in solid state at 375 nm displays red emission. Moreover, variable temperature magnetic susceptibility measurements indicate that the magnetic behavior in compound 1 is dominated by antiferromagnetic interactions. Frontiers Media S.A. 2021-02-19 /pmc/articles/PMC7935544/ /pubmed/33681143 http://dx.doi.org/10.3389/fchem.2021.615595 Text en Copyright © 2021 Zhao, Sun, Ji, Kong, Chen, Ma, Niu and Wang. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Zhao, Yanxin
Sun, Xiaopeng
Ji, Yanfang
Kong, Hui
Chen, Shumin
Ma, Pengtao
Niu, Jingyang
Wang, Jingping
A 3D Silverton-Type Polyoxomolybdate Based on {PrMo(12)O(42)}: Synthesis, Structure, Photoluminescence and Magnetic Properties
title A 3D Silverton-Type Polyoxomolybdate Based on {PrMo(12)O(42)}: Synthesis, Structure, Photoluminescence and Magnetic Properties
title_full A 3D Silverton-Type Polyoxomolybdate Based on {PrMo(12)O(42)}: Synthesis, Structure, Photoluminescence and Magnetic Properties
title_fullStr A 3D Silverton-Type Polyoxomolybdate Based on {PrMo(12)O(42)}: Synthesis, Structure, Photoluminescence and Magnetic Properties
title_full_unstemmed A 3D Silverton-Type Polyoxomolybdate Based on {PrMo(12)O(42)}: Synthesis, Structure, Photoluminescence and Magnetic Properties
title_short A 3D Silverton-Type Polyoxomolybdate Based on {PrMo(12)O(42)}: Synthesis, Structure, Photoluminescence and Magnetic Properties
title_sort 3d silverton-type polyoxomolybdate based on {prmo(12)o(42)}: synthesis, structure, photoluminescence and magnetic properties
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7935544/
https://www.ncbi.nlm.nih.gov/pubmed/33681143
http://dx.doi.org/10.3389/fchem.2021.615595
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