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Unusual hydrogen implanted gold with lattice contraction at increased hydrogen content

The experimental evidence for the contraction of volume of gold implanted with hydrogen at low doses is presented. The contraction of lattice upon the addition of other elements is very rare and extraordinary in the solid-state, not only for gold but also for many other solids. To explain the underl...

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Detalles Bibliográficos
Autores principales: Nguyen, Khac Thuan, Hiep Vuong, Van, Nguyen, The Nghia, Nguyen, Trong Tinh, Yamamoto, Tomoyuki, Hoang, Nam Nhat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7946955/
https://www.ncbi.nlm.nih.gov/pubmed/33692353
http://dx.doi.org/10.1038/s41467-021-21842-9
Descripción
Sumario:The experimental evidence for the contraction of volume of gold implanted with hydrogen at low doses is presented. The contraction of lattice upon the addition of other elements is very rare and extraordinary in the solid-state, not only for gold but also for many other solids. To explain the underlying physics, the pure kinetic theory of absorption is not adequate and the detailed interaction of hydrogen in the lattice needs to be clarified. Our analysis points to the importance of the formation of hydride bonds in a dynamic manner and explains why these bonds become weak at higher doses, leading to the inverse process of volume expansion frequently seen in metallic hydrogen containers.