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Fabrication of Mesoporous PtO–ZnO Nanocomposites with Promoted Photocatalytic Performance for Degradation of Tetracycline

[Image: see text] Herein, we report a simple incorporation of PtO NPs at diverse percentages (0.2–0.8 wt %) onto a highly crystalline and mesoporous ZnO matrix by the wet-impregnation approach for degradation of tetracycline (TC) upon visible light exposure. These well-dispersed and small-sized PtO...

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Autores principales: Mohamed, Reda M., Ismail, Adel A., Kadi, Mohammad W., Alresheedi, Ajayb S., Mkhalid, Ibraheem A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7948444/
https://www.ncbi.nlm.nih.gov/pubmed/33718734
http://dx.doi.org/10.1021/acsomega.1c00135
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author Mohamed, Reda M.
Ismail, Adel A.
Kadi, Mohammad W.
Alresheedi, Ajayb S.
Mkhalid, Ibraheem A.
author_facet Mohamed, Reda M.
Ismail, Adel A.
Kadi, Mohammad W.
Alresheedi, Ajayb S.
Mkhalid, Ibraheem A.
author_sort Mohamed, Reda M.
collection PubMed
description [Image: see text] Herein, we report a simple incorporation of PtO NPs at diverse percentages (0.2–0.8 wt %) onto a highly crystalline and mesoporous ZnO matrix by the wet-impregnation approach for degradation of tetracycline (TC) upon visible light exposure. These well-dispersed and small-sized PtO NPs provide the mesoporous PtO–ZnO nanocomposites with outstanding photocatalytic performance for complete TC degradation. The optimized 0.6% PtO–ZnO photocatalyst exhibits excellent TC degradation, and its degradation efficiency reached ∼99% within 120 min. The photocatalytic performance of the 0.6% PtO–ZnO nanocomposite is 20 and 10 times higher than that of pristine ZnO and commercial P-25, respectively. The photodegradation rate of TC over the 0.6% PtO–ZnO nanocomposite is 34 and 12.5 times greater than that of pristine ZnO and commercial P-25, respectively. This is because of the large surface area, unique porous structure, synergistic effect, and broad visible light absorption of the PtO–ZnO nanocomposite. Moreover, mesoporous PtO–ZnO nanocomposites showed a high stability and recyclability over five iterations. This work demonstrates the remarkable role of combining PtO and ZnO photocatalysts in providing nanocomposites with significant potential for the preservation of human health through wastewater remediation.
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spelling pubmed-79484442021-03-12 Fabrication of Mesoporous PtO–ZnO Nanocomposites with Promoted Photocatalytic Performance for Degradation of Tetracycline Mohamed, Reda M. Ismail, Adel A. Kadi, Mohammad W. Alresheedi, Ajayb S. Mkhalid, Ibraheem A. ACS Omega [Image: see text] Herein, we report a simple incorporation of PtO NPs at diverse percentages (0.2–0.8 wt %) onto a highly crystalline and mesoporous ZnO matrix by the wet-impregnation approach for degradation of tetracycline (TC) upon visible light exposure. These well-dispersed and small-sized PtO NPs provide the mesoporous PtO–ZnO nanocomposites with outstanding photocatalytic performance for complete TC degradation. The optimized 0.6% PtO–ZnO photocatalyst exhibits excellent TC degradation, and its degradation efficiency reached ∼99% within 120 min. The photocatalytic performance of the 0.6% PtO–ZnO nanocomposite is 20 and 10 times higher than that of pristine ZnO and commercial P-25, respectively. The photodegradation rate of TC over the 0.6% PtO–ZnO nanocomposite is 34 and 12.5 times greater than that of pristine ZnO and commercial P-25, respectively. This is because of the large surface area, unique porous structure, synergistic effect, and broad visible light absorption of the PtO–ZnO nanocomposite. Moreover, mesoporous PtO–ZnO nanocomposites showed a high stability and recyclability over five iterations. This work demonstrates the remarkable role of combining PtO and ZnO photocatalysts in providing nanocomposites with significant potential for the preservation of human health through wastewater remediation. American Chemical Society 2021-02-23 /pmc/articles/PMC7948444/ /pubmed/33718734 http://dx.doi.org/10.1021/acsomega.1c00135 Text en © 2021 The Authors. Published by American Chemical Society This is an open access article published under an ACS AuthorChoice License (https://creativecommons.org/licenses/by-nc-nd/4.0/) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Mohamed, Reda M.
Ismail, Adel A.
Kadi, Mohammad W.
Alresheedi, Ajayb S.
Mkhalid, Ibraheem A.
Fabrication of Mesoporous PtO–ZnO Nanocomposites with Promoted Photocatalytic Performance for Degradation of Tetracycline
title Fabrication of Mesoporous PtO–ZnO Nanocomposites with Promoted Photocatalytic Performance for Degradation of Tetracycline
title_full Fabrication of Mesoporous PtO–ZnO Nanocomposites with Promoted Photocatalytic Performance for Degradation of Tetracycline
title_fullStr Fabrication of Mesoporous PtO–ZnO Nanocomposites with Promoted Photocatalytic Performance for Degradation of Tetracycline
title_full_unstemmed Fabrication of Mesoporous PtO–ZnO Nanocomposites with Promoted Photocatalytic Performance for Degradation of Tetracycline
title_short Fabrication of Mesoporous PtO–ZnO Nanocomposites with Promoted Photocatalytic Performance for Degradation of Tetracycline
title_sort fabrication of mesoporous pto–zno nanocomposites with promoted photocatalytic performance for degradation of tetracycline
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7948444/
https://www.ncbi.nlm.nih.gov/pubmed/33718734
http://dx.doi.org/10.1021/acsomega.1c00135
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