Vinyl ethers and epoxides photoinduced copolymerization with perfluoropolyalkylether monomers

New perfluoropolyalkylether (PFPAE) monomers, chain extended with different alkyl groups and functionalized with vinyl ether or epoxide end-groups, were employed, together with trimethylolpropane trivinyl ether or trimethylolpropane triglycidyl ether, to produce fluorinated copolymers. The photoindu...

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Autores principales: Trusiano, Giuseppe, Vitale, Alessandra, Bonneaud, Céline, Pugliese, Diego, Dalle Vacche, Sara, Joly-Duhamel, Christine, Friesen, Chadron M., Bongiovanni, Roberta
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Berlin Heidelberg 2020
Materias:
Invited Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7952294/
https://www.ncbi.nlm.nih.gov/pubmed/33785978
http://dx.doi.org/10.1007/s00396-020-04723-3
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author Trusiano, Giuseppe
Vitale, Alessandra
Bonneaud, Céline
Pugliese, Diego
Dalle Vacche, Sara
Joly-Duhamel, Christine
Friesen, Chadron M.
Bongiovanni, Roberta
author_facet Trusiano, Giuseppe
Vitale, Alessandra
Bonneaud, Céline
Pugliese, Diego
Dalle Vacche, Sara
Joly-Duhamel, Christine
Friesen, Chadron M.
Bongiovanni, Roberta
author_sort Trusiano, Giuseppe
collection PubMed
description New perfluoropolyalkylether (PFPAE) monomers, chain extended with different alkyl groups and functionalized with vinyl ether or epoxide end-groups, were employed, together with trimethylolpropane trivinyl ether or trimethylolpropane triglycidyl ether, to produce fluorinated copolymers. The photoinduced cationic polymerization was investigated, and the PFPAE-based copolymer properties were thoroughly characterized. Interesting surface properties and two different values of refractive index were observed: thus, these fluorinated copolymers can be suitable materials for the manufacture of self-cleaning coatings and optical waveguides. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (10.1007/s00396-020-04723-3) contains supplementary material, which is available to authorized users.
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spelling pubmed-79522942021-03-28 Vinyl ethers and epoxides photoinduced copolymerization with perfluoropolyalkylether monomers Trusiano, Giuseppe Vitale, Alessandra Bonneaud, Céline Pugliese, Diego Dalle Vacche, Sara Joly-Duhamel, Christine Friesen, Chadron M. Bongiovanni, Roberta Colloid Polym Sci Invited Article New perfluoropolyalkylether (PFPAE) monomers, chain extended with different alkyl groups and functionalized with vinyl ether or epoxide end-groups, were employed, together with trimethylolpropane trivinyl ether or trimethylolpropane triglycidyl ether, to produce fluorinated copolymers. The photoinduced cationic polymerization was investigated, and the PFPAE-based copolymer properties were thoroughly characterized. Interesting surface properties and two different values of refractive index were observed: thus, these fluorinated copolymers can be suitable materials for the manufacture of self-cleaning coatings and optical waveguides. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (10.1007/s00396-020-04723-3) contains supplementary material, which is available to authorized users. Springer Berlin Heidelberg 2020-09-09 2021 /pmc/articles/PMC7952294/ /pubmed/33785978 http://dx.doi.org/10.1007/s00396-020-04723-3 Text en © The Author(s) 2020 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Invited Article
Trusiano, Giuseppe
Vitale, Alessandra
Bonneaud, Céline
Pugliese, Diego
Dalle Vacche, Sara
Joly-Duhamel, Christine
Friesen, Chadron M.
Bongiovanni, Roberta
Vinyl ethers and epoxides photoinduced copolymerization with perfluoropolyalkylether monomers
title Vinyl ethers and epoxides photoinduced copolymerization with perfluoropolyalkylether monomers
title_full Vinyl ethers and epoxides photoinduced copolymerization with perfluoropolyalkylether monomers
title_fullStr Vinyl ethers and epoxides photoinduced copolymerization with perfluoropolyalkylether monomers
title_full_unstemmed Vinyl ethers and epoxides photoinduced copolymerization with perfluoropolyalkylether monomers
title_short Vinyl ethers and epoxides photoinduced copolymerization with perfluoropolyalkylether monomers
title_sort vinyl ethers and epoxides photoinduced copolymerization with perfluoropolyalkylether monomers
topic Invited Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7952294/
https://www.ncbi.nlm.nih.gov/pubmed/33785978
http://dx.doi.org/10.1007/s00396-020-04723-3
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