A shift from anaerobic digestion to dark fermentation in glycol ethylene fermentation

Anaerobic digestion of aqueous glycol ethylene was tested. The process lasted two cycles of 7 days, but after the second cycle, high hydrogen production occurred shift to dark fermentation. The biogas production lasted 14 days, obtaining peak values of hydrogen, and then rapidly stopped. In investigations, the following were checked: dependence of hydrogen, methane and hydrogen sulphide in the process. Mixtures of water with glycol ethylene mass ratio from 0.6 to 0.85 were substrates in experiments. The highest methane production was for water ethylene 0.7 ratio 2.85 L of methane with a yield of 178 mL of methane/g VSS (volatile suspended solids) of glycol ethylene. The optimal ratio of water and glycol ethylene was 0.85 25.5 mL of hydrogen (giving yield 1.71 mL of hydrogen/g VSS of glycol ethylene) and 1.71 mL of hydrogen sulphide emission for a 0.6 ratio. Popular polymer industry wastes, glycol ethylene, can be utilised by anaerobic digestion.