Effect of Iodine Filler on Photoisomerization Kinetics of Photo-Switchable Thin Films Based on PEO-BDK-MR

We report the effect of an iodine filler on photoisomerization kinetics of photo-switchable PEO-BDK-MR thin films. The kinetics of photoisomerization and time progression of PEO-BDK-MR/I(2) nanocomposite thin films are investigated using UV-Vis, FTIR spectroscopies, and modified mathematical models...

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Autores principales: Al-Bataineh, Qais M., Ahmad, A. A., Alsaad, A. M., Qattan, I. A., Aljarrah, Ihsan A., Telfah, Ahmad D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7967190/
https://www.ncbi.nlm.nih.gov/pubmed/33803395
http://dx.doi.org/10.3390/polym13050841
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author Al-Bataineh, Qais M.
Ahmad, A. A.
Alsaad, A. M.
Qattan, I. A.
Aljarrah, Ihsan A.
Telfah, Ahmad D.
author_facet Al-Bataineh, Qais M.
Ahmad, A. A.
Alsaad, A. M.
Qattan, I. A.
Aljarrah, Ihsan A.
Telfah, Ahmad D.
author_sort Al-Bataineh, Qais M.
collection PubMed
description We report the effect of an iodine filler on photoisomerization kinetics of photo-switchable PEO-BDK-MR thin films. The kinetics of photoisomerization and time progression of PEO-BDK-MR/I(2) nanocomposite thin films are investigated using UV-Vis, FTIR spectroscopies, and modified mathematical models developed using new analytical methods. Incorporating iodine filler into the PEO-BDK-MR polymeric matrix enhances the isomerization energy barrier and considerably increases the processing time. Our outcomes propose that enhanced photoisomerized and time processed (PEO-BDK-MR)/I(2) thin films could be potential candidates for a variety of applications involving molecular solar thermal energy storage media.
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spelling pubmed-79671902021-03-18 Effect of Iodine Filler on Photoisomerization Kinetics of Photo-Switchable Thin Films Based on PEO-BDK-MR Al-Bataineh, Qais M. Ahmad, A. A. Alsaad, A. M. Qattan, I. A. Aljarrah, Ihsan A. Telfah, Ahmad D. Polymers (Basel) Article We report the effect of an iodine filler on photoisomerization kinetics of photo-switchable PEO-BDK-MR thin films. The kinetics of photoisomerization and time progression of PEO-BDK-MR/I(2) nanocomposite thin films are investigated using UV-Vis, FTIR spectroscopies, and modified mathematical models developed using new analytical methods. Incorporating iodine filler into the PEO-BDK-MR polymeric matrix enhances the isomerization energy barrier and considerably increases the processing time. Our outcomes propose that enhanced photoisomerized and time processed (PEO-BDK-MR)/I(2) thin films could be potential candidates for a variety of applications involving molecular solar thermal energy storage media. MDPI 2021-03-09 /pmc/articles/PMC7967190/ /pubmed/33803395 http://dx.doi.org/10.3390/polym13050841 Text en © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Al-Bataineh, Qais M.
Ahmad, A. A.
Alsaad, A. M.
Qattan, I. A.
Aljarrah, Ihsan A.
Telfah, Ahmad D.
Effect of Iodine Filler on Photoisomerization Kinetics of Photo-Switchable Thin Films Based on PEO-BDK-MR
title Effect of Iodine Filler on Photoisomerization Kinetics of Photo-Switchable Thin Films Based on PEO-BDK-MR
title_full Effect of Iodine Filler on Photoisomerization Kinetics of Photo-Switchable Thin Films Based on PEO-BDK-MR
title_fullStr Effect of Iodine Filler on Photoisomerization Kinetics of Photo-Switchable Thin Films Based on PEO-BDK-MR
title_full_unstemmed Effect of Iodine Filler on Photoisomerization Kinetics of Photo-Switchable Thin Films Based on PEO-BDK-MR
title_short Effect of Iodine Filler on Photoisomerization Kinetics of Photo-Switchable Thin Films Based on PEO-BDK-MR
title_sort effect of iodine filler on photoisomerization kinetics of photo-switchable thin films based on peo-bdk-mr
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7967190/
https://www.ncbi.nlm.nih.gov/pubmed/33803395
http://dx.doi.org/10.3390/polym13050841
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