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Constructing Hierarchically Porous N-Doped Carbons Derived from Poly(ionic liquids) with the Multifunctional Fe-Based Template for CO(2) Adsorption

[Image: see text] Nitrogen-doped hierarchical porous carbons with a rich pore structure were prepared via direct carbonization of the poly(ionic liquid) (PIL)/potassium ferricyanide compound. Thereinto, the bisvinylimidazolium-based PIL was a desirable carbon source, and potassium ferricyanide as a...

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Autores principales: Guo, Qirui, Chen, Chong, Xing, Fangcheng, Shi, Weizhong, Meng, Jie, Wan, Hui, Guan, Guofeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7970570/
https://www.ncbi.nlm.nih.gov/pubmed/33748633
http://dx.doi.org/10.1021/acsomega.1c00419
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author Guo, Qirui
Chen, Chong
Xing, Fangcheng
Shi, Weizhong
Meng, Jie
Wan, Hui
Guan, Guofeng
author_facet Guo, Qirui
Chen, Chong
Xing, Fangcheng
Shi, Weizhong
Meng, Jie
Wan, Hui
Guan, Guofeng
author_sort Guo, Qirui
collection PubMed
description [Image: see text] Nitrogen-doped hierarchical porous carbons with a rich pore structure were prepared via direct carbonization of the poly(ionic liquid) (PIL)/potassium ferricyanide compound. Thereinto, the bisvinylimidazolium-based PIL was a desirable carbon source, and potassium ferricyanide as a multifunctional Fe-based template, could not only serve as the pore-forming agent, including metallic components (Fe and Fe(3)C), potassium ions (etching carbon framework during carbonization), and gas generated during the pyrolysis process, but also introduce the N atoms to porous carbons, which were in favor of CO(2) capture. Moreover, the hierarchically porous carbon NDPC-1-800 (NDPC, nitrogen-doped porous carbon) had taken advantage of the highest specific surface area, exhibiting an excellent CO(2) adsorption capacity and selectivity compared with NDC-800 (NDC, nitrogen-doped carbon) directly carbonized from the pure PIL. Furthermore, its hierarchical porous architectures played an important part in the process of CO(2) capture, which was described briefly as follows: the synergistic effect of mesopores and micropores could accelerate the CO(2) molecules’ transportation and storage. Meanwhile, the appropriate microporous size distribution of NDPC-1-800 was conducive to enhancing CO(2)/N(2) selectivity. This study was intended to open up a new pathway for designing N-doped porous carbons combining both PILs and the multifunctional Fe-based template potassium ferricyanide with wonderful gas adsorption and separation performance.
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spelling pubmed-79705702021-03-19 Constructing Hierarchically Porous N-Doped Carbons Derived from Poly(ionic liquids) with the Multifunctional Fe-Based Template for CO(2) Adsorption Guo, Qirui Chen, Chong Xing, Fangcheng Shi, Weizhong Meng, Jie Wan, Hui Guan, Guofeng ACS Omega [Image: see text] Nitrogen-doped hierarchical porous carbons with a rich pore structure were prepared via direct carbonization of the poly(ionic liquid) (PIL)/potassium ferricyanide compound. Thereinto, the bisvinylimidazolium-based PIL was a desirable carbon source, and potassium ferricyanide as a multifunctional Fe-based template, could not only serve as the pore-forming agent, including metallic components (Fe and Fe(3)C), potassium ions (etching carbon framework during carbonization), and gas generated during the pyrolysis process, but also introduce the N atoms to porous carbons, which were in favor of CO(2) capture. Moreover, the hierarchically porous carbon NDPC-1-800 (NDPC, nitrogen-doped porous carbon) had taken advantage of the highest specific surface area, exhibiting an excellent CO(2) adsorption capacity and selectivity compared with NDC-800 (NDC, nitrogen-doped carbon) directly carbonized from the pure PIL. Furthermore, its hierarchical porous architectures played an important part in the process of CO(2) capture, which was described briefly as follows: the synergistic effect of mesopores and micropores could accelerate the CO(2) molecules’ transportation and storage. Meanwhile, the appropriate microporous size distribution of NDPC-1-800 was conducive to enhancing CO(2)/N(2) selectivity. This study was intended to open up a new pathway for designing N-doped porous carbons combining both PILs and the multifunctional Fe-based template potassium ferricyanide with wonderful gas adsorption and separation performance. American Chemical Society 2021-03-03 /pmc/articles/PMC7970570/ /pubmed/33748633 http://dx.doi.org/10.1021/acsomega.1c00419 Text en © 2021 The Authors. Published by American Chemical Society Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Guo, Qirui
Chen, Chong
Xing, Fangcheng
Shi, Weizhong
Meng, Jie
Wan, Hui
Guan, Guofeng
Constructing Hierarchically Porous N-Doped Carbons Derived from Poly(ionic liquids) with the Multifunctional Fe-Based Template for CO(2) Adsorption
title Constructing Hierarchically Porous N-Doped Carbons Derived from Poly(ionic liquids) with the Multifunctional Fe-Based Template for CO(2) Adsorption
title_full Constructing Hierarchically Porous N-Doped Carbons Derived from Poly(ionic liquids) with the Multifunctional Fe-Based Template for CO(2) Adsorption
title_fullStr Constructing Hierarchically Porous N-Doped Carbons Derived from Poly(ionic liquids) with the Multifunctional Fe-Based Template for CO(2) Adsorption
title_full_unstemmed Constructing Hierarchically Porous N-Doped Carbons Derived from Poly(ionic liquids) with the Multifunctional Fe-Based Template for CO(2) Adsorption
title_short Constructing Hierarchically Porous N-Doped Carbons Derived from Poly(ionic liquids) with the Multifunctional Fe-Based Template for CO(2) Adsorption
title_sort constructing hierarchically porous n-doped carbons derived from poly(ionic liquids) with the multifunctional fe-based template for co(2) adsorption
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7970570/
https://www.ncbi.nlm.nih.gov/pubmed/33748633
http://dx.doi.org/10.1021/acsomega.1c00419
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