Solution-Processed All-inorganic Planar Heterojunction Solar Cells by Employing In Situ Grown Interfacial Layer with Dual Functions: Complementary Absorption and Selective Extraction of Photogenerated Holes

[Image: see text] Photovoltaic conversion of renewable solar energy into electricity for sustainable energy production requires efficient, stable, and low-cost solar cells. Developing solution-processed all-inorganic solar cells is a practical scenario in virtue of the high charge mobility and good stability of inorganic semiconductors. Here, for the first time, we present a solution-processed all-inorganic planar heterojunction solar cell based on the nanoparticle film of copper indium sulfide (CuInS(2)) by using an antimony trisulfide (Sb(2)S(3)) nanoparticle film as an interfacial layer between the CuInS(2) photon-harvesting layer and cathode. All of the component layers in the solar cell are in a superstrate architecture and sequentially in situ grown on a transparent conducting glass acting as anode by solution-processing methods. The dependences of device performance on the thickness of Sb(2)S(3) film and the reduction of hole-trapping centers in the Sb(2)S(3) film by thioacetamide treatment are investigated. The optimized all-inorganic device exhibits the best power conversion efficiency of 4.85% under AM 1.5G illumination and an excellent thermal stability. It is found that the Sb(2)S(3) interfacial layer sandwiched between the CuInS(2) photon-harvesting layer and counter-electrode has dual functions, that is, to provide complementary absorption after CuInS(2) attenuation and to act as an effective hole-transporting layer to selectively extract photogenerated holes for effective charge collection efficiency.