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Formal Enone α-Arylation via I(III)-Mediated Aryl Migration/Elimination
[Image: see text] A formal enone α-arylation is described. This metal-free transformation relies on the I(III)-mediated skeletal reorganization of silyl enol ethers and features mild conditions, good yields, and high stereoselectivities for β-substituted enones.
Autores principales: | Martins, Bruna S., Kaiser, Daniel, Bauer, Adriano, Tiefenbrunner, Irmgard, Maulide, Nuno |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7985840/ https://www.ncbi.nlm.nih.gov/pubmed/33635665 http://dx.doi.org/10.1021/acs.orglett.1c00251 |
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