Cargando…

Synthesis and Hydrogenation of Heavy Homologues of Rhodium Carbynes: [(Me(3)P)(2)(Ph(3)P)Rh≡E‐Ar*] (E=Sn, Pb)

Tetrylidynes [(Me(3)P)(2)(Ph(3)P)Rh≡SnAr*] (10) and [(Me(3)P)(2)(Ph(3)P)Rh≡PbAr*] (11) are accessed for the first time via dehydrogenation of dihydrides [(Ph(3)P)(2)RhH(2)SnAr*] (3) and [(Ph(3)P)(2)RhH(2)PbAr*] (7) (Ar*=2,6‐Trip(2)C(6)H(3), Trip=2,4,6‐triisopropylphenyl), respectively. Tin dihydride...

Descripción completa

Detalles Bibliográficos
Autores principales:	Widemann, Max, Eichele, Klaus, Schubert, Hartmut, Sindlinger, Christian P., Klenner, Steffen, Pöttgen, Rainer, Wesemann, Lars
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986155/ https://www.ncbi.nlm.nih.gov/pubmed/33438371 http://dx.doi.org/10.1002/anie.202015725

Ejemplares similares

Hydridotetrylene [Ar*EH] (E = Ge, Sn, Pb) coordination at tantalum, tungsten, and zirconium
por: Widemann, Max, et al.
Publicado: (2022)

Molecular Ln(III)−H−E(II) Linkages (Ln=Y, Lu; E=Ge, Sn, Pb)
por: Widemann, Max, et al.
Publicado: (2022)

Synthesis and structure of a family of rhodium polystannide clusters [Rh@Sn(10)](3–), [Rh@Sn(12)](3–), [Rh(2)@Sn(17)](6–) and the first triply-fused stannide, [Rh(3)@Sn(24)](5–)
por: Liu, Chao, et al.
Publicado: (2019)

Heavy metalla vinyl-cations show metal–Lewis acid cooperativity in reaction with small molecules (NH(3), N(2)H(4), H(2)O, H(2))
por: Auer, Maximilian, et al.
Publicado: (2022)

The Highest Oxidation State of Rhodium: Rhodium(VII) in [RhO(3)](+)
por: da Silva Santos, Mayara, et al.
Publicado: (2022)

Carbyne and carbynoid structures
por: Heimann, Robert, et al.
Publicado: (1999)

Hole Transfer in Open Carbynes
por: Simserides, Constantinos, et al.
Publicado: (2020)

Mechanical properties of carbyne: experiment and simulations
por: Kotrechko, Sergiy, et al.
Publicado: (2015)

Thermomechanical Stability of Carbyne-Based Nanodevices
por: Kotrechko, Sergiy, et al.
Publicado: (2017)

Recent Advances in the Reactions of Cyclic Carbynes
por: Su, Qian, et al.
Publicado: (2020)

Hydridoorganostannylene Coordination: Group 4 Metallocene Dichloride Reduction in Reaction with Organodihydridostannate Anions
por: Maudrich, Jakob‐Jonathan, et al.
Publicado: (2019)

Addition of alkynes and osmium carbynes towards functionalized d(π)–p(π) conjugated systems
por: Chen, Shiyan, et al.
Publicado: (2020)

Thermal stability of idealized folded carbyne loops
por: Cranford, Steven W
Publicado: (2013)

Optical gap and fundamental gap of oligoynes and carbyne
por: Zirzlmeier, Johannes, et al.
Publicado: (2020)

Overview of the Metallization Approaches for Carbyne-Based Devices
por: Tomov, Rade, et al.
Publicado: (2023)

Ge=B π‐Bonding: Synthesis and Reversible [2+2] Cycloaddition of Germaborenes
por: Raiser, Dominik, et al.
Publicado: (2020)

Carbyne with finite length: The one-dimensional sp carbon
por: Pan, Bitao, et al.
Publicado: (2015)

Functional Promiscuity of Homologues of the Bacterial ArsA ATPases
por: Castillo, Rostislav, et al.
Publicado: (2010)

Rh(2)(CF(3)CONH)(4): The First Biological Assays of a Rhodium (II) Amidate
por: Espósito, Breno Pannia, et al.
Publicado: (1997)

Regioselectivity of the S(E)Ar-based cyclizations and S(E)Ar-terminated annulations of 3,5-unsubstituted, 4-substituted indoles
por: Das, Jonali, et al.
Publicado: (2022)

Phosphine‐Stabilized Pnictinidenes
por: Raiser, Dominik, et al.
Publicado: (2021)

Tip-Enhanced Stokes–Anti-Stokes Scattering from Carbyne
por: Tschannen, Cla Duri, et al.
Publicado: (2022)

Metallothionein: An Aggressive Scavenger—The Metabolism of Rhodium(II) Tetraacetate (Rh(2)(CH(3)CO(2))(4))
por: Wong, Daisy L., et al.
Publicado: (2018)

Quadruple C–H Bond Activations of Methane by Dinuclear Rhodium Carbide Cation [Rh(2)C(3)](+)
por: Wu, Hechen, et al.
Publicado: (2021)

Di-μ-carbonyl-bis[bis(triphenylphosphane)rhodium(0)](Rh—Rh) acetone disolvate
por: Gueorguieva, Petia G., et al.
Publicado: (2012)

Structure of high spin states in $^{104}$Sn: E2 and E3 polarization of the $^{100}Sn$ core
por: Górska, M, et al.
Publicado: (1998)

Proceedings of the NATO Advanced Research Workshop on Transition Metal Carbyne Complexes
por: Kreißl, F
Publicado: (1993)

Carbyne Polysulfide as a Novel Cathode Material for Rechargeable Magnesium Batteries
por: NuLi, Yanna, et al.
Publicado: (2014)

Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion
por: Luo, Ming, et al.
Publicado: (2016)

Influence of Carbyne Content on the Mechanical Performance of Nanothick Amorphous Carbon Coatings
por: Piedade, Ana P., et al.
Publicado: (2020)

The kinked structure and interchain van der Waals interaction of carbyne nanocrystals
por: Cao, Weiwei, et al.
Publicado: (2022)

Total Synthesis, Structure, and Biological Activity of Adenosylrhodibalamin, the Non‐Natural Rhodium Homologue of Coenzyme B(12)
por: Widner, Florian J., et al.
Publicado: (2016)

Scalable Synthesis of Esp and Rhodium(II) Carboxylates from Acetylacetone and RhCl(3)·xH(2)O
por: Martínez-Castro, Elisa, et al.
Publicado: (2020)

Regulation of p53 by E3s
por: Pan, Mengwu, et al.
Publicado: (2021)

The Weak 3D Topological Insulator Bi(12)Rh(3)Sn(3)I(9)
por: Lê Anh, Mai, et al.
Publicado: (2020)

Is there a $\beta$3p branch in the decay of $^{31}$Ar?
por: Fynbo, H O U, et al.
Publicado: (1998)

Dipyrromethane‐Based PGeP Pincer Germyl Rhodium Complexes
por: Cabeza, Javier A., et al.
Publicado: (2022)

Carbyne Ring Activated Using ZnCl(2) for Hydrogen Adsorption: DFT Study
por: Desales Guzmán, Luis Alberto, et al.
Publicado: (2022)

Extension of the Simmons–Smith reaction to metal-carbynes: efficient synthesis of metallacyclopropenes with σ-aromaticity
por: Huang, Fanping, et al.
Publicado: (2020)

Sizeable beta-strength in 31Ar(beta-3p) decay
por: Koldste, G.T., et al.
Publicado: (2014)

Cannot write session to /tmp/vufind_sessions/sess_nn6ecje9klm0vgcu7mjfduhb1t