Cargando…

Electrooxidative Rhodium‐Catalyzed [5+2] Annulations via C−H/O−H Activations

Electrooxidative annulations involving mild transition metal‐catalyzed C−H activation have emerged as a transformative strategy for the rapid construction of five‐ and six‐membered heterocycles. In contrast, we herein describe the first electrochemical metal‐catalyzed [5+2] cycloadditions to assembl...

Descripción completa

Detalles Bibliográficos
Autores principales:	Wang, Yulei, Oliveira, João C. A., Lin, Zhipeng, Ackermann, Lutz
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986427/ https://www.ncbi.nlm.nih.gov/pubmed/33471952 http://dx.doi.org/10.1002/anie.202016895

Ejemplares similares

Rhodium‐Catalyzed Electrooxidative C−H Olefination of Benzamides
por: Zhang, Yan, et al.
Publicado: (2020)

Electrooxidative palladium- and enantioselective rhodium-catalyzed [3 + 2] spiroannulations
por: Wei, Wen, et al.
Publicado: (2022)

Cobalt-catalyzed electrooxidative C-H/N-H [4+2] annulation with ethylene or ethyne
por: Tang, Shan, et al.
Publicado: (2018)

Divergent rhodium-catalyzed electrochemical vinylic C–H annulation of acrylamides with alkynes
por: Xing, Yi-Kang, et al.
Publicado: (2021)

All-Carbon [3+3] Oxidative Annulations of 1,3-Enynes by Rhodium(III)-Catalyzed C–H Functionalization and 1,4-Migration**
por: Burns, David J, et al.
Publicado: (2015)

Rhodium(III)-Catalyzed [4+2] Annulation via C-H Activation: Synthesis of Multi-Substituted Naphthalenone Sulfoxonium Ylides
por: Song, Xiaohan, et al.
Publicado: (2019)

Rhodium-catalyzed annulative approach to N–N axially chiral biaryls via C–H activation and dynamic kinetic transformation
por: Zhu, Xiaohan, et al.
Publicado: (2023)

Intramolecular cascade annulation triggered by rhodium(III)-catalyzed sequential C(sp(2))–H activation and C(sp(3))–H amination
por: Song, Liangliang, et al.
Publicado: (2019)

π‐Extended Polyaromatic Hydrocarbons by Sustainable Alkyne Annulations through Double C−H/N−H Activation
por: Gońka, Elżbieta, et al.
Publicado: (2019)

Rhodium(iii)-catalyzed C–H annulation of 2-acetyl-1-arylhydrazines with sulfoxonium ylides: synthesis of 2-arylindoles
por: Li, He, et al.
Publicado: (2020)

Synthesis of 2,5-diaryloxazoles through rhodium-catalyzed annulation of triazoles and aldehydes
por: Li, Jian, et al.
Publicado: (2020)

Distal Ruthenaelectro‐Catalyzed meta‐C−H Bromination with Aqueous HBr
por: Wang, Yulei, et al.
Publicado: (2022)

Ruthenaelectro‐Catalyzed Domino Three‐Component Alkyne Annulation for Expedient Isoquinoline Assembly
por: Tan, Xuefeng, et al.
Publicado: (2021)

Synthesis of Di-, Tri-, and Tetrasubstituted Oxetanes by Rhodium-Catalyzed O=H Insertion and C=C Bond-Forming Cyclization**
por: Davis, Owen A, et al.
Publicado: (2014)

Rhodium(iii)-catalyzed diverse [4 + 1] annulation of arenes with 1,3-enynes via sp(3)/sp(2) C–H activation and 1,4-rhodium migration
por: Bai, Dachang, et al.
Publicado: (2019)

Copper-catalyzed CuAAC/intramolecular C–H arylation sequence: Synthesis of annulated 1,2,3-triazoles
por: Jeyachandran, Rajkumar, et al.
Publicado: (2012)

Rhodium(III)-Catalyzed Intramolecular Annulations of Acrylic and Benzoic Acids to Alkynes
por: F. Fernández, David, et al.
Publicado: (2019)

Rhodium(iii)-catalyzed annulation of enamides with sulfoxonium ylides toward isoquinolines
por: Hong, Chao, et al.
Publicado: (2021)

Enantioselective Synthesis of Spiroindenes by Enol-Directed Rhodium(III)-Catalyzed C–H Functionalization and Spiroannulation
por: Reddy Chidipudi, Suresh, et al.
Publicado: (2015)

Rhodium(III)-Catalyzed Dearomatizing (3 + 2) Annulation of 2-Alkenylphenols and Alkynes
por: Seoane, Andrés, et al.
Publicado: (2014)

Diastereoselective Carbocyclization of 1,6-Heptadienes Triggered by Rhodium-Catalyzed Activation of an Olefinic C=H Bond**
por: Aïssa, Christophe, et al.
Publicado: (2014)

Evolution of High‐Valent Nickela‐Electrocatalyzed C−H Activation: From Cross(‐Electrophile)‐Couplings to Electrooxidative C−H Transformations
por: Zhang, Shou‐Kun, et al.
Publicado: (2020)

Catalytic 1,4-Rhodium(III) Migration Enables 1,3-Enynes to Function as One-Carbon Oxidative Annulation Partners in C–H Functionalizations**
por: Burns, David J, et al.
Publicado: (2014)

Isomerization of Olefins Triggered by Rhodium-Catalyzed C–H Bond Activation: Control of Endocyclic β-Hydrogen Elimination**
por: Yip, Stephanie Y Y, et al.
Publicado: (2015)

Photo‐Induced Ruthenium‐Catalyzed Double Remote C(sp(2))−H / C(sp(3))−H Functionalizations by Radical Relay
por: Wang, Yulei, et al.
Publicado: (2022)

Iron‐Catalyzed C−H Activation with Propargyl Acetates: Mechanistic Insights into Iron(II) by Experiment, Kinetics, Mössbauer Spectroscopy, and Computation
por: Mo, Jiayu, et al.
Publicado: (2019)

Selective Labeling of Peptides with o‐Carboranes via Manganese(I)‐Catalyzed C−H Activation
por: Jei, Becky Bongsuiru, et al.
Publicado: (2022)

Rhodium catalyzed template-assisted distal para-C–H olefination
por: Dutta, Uttam, et al.
Publicado: (2019)

[2+2+2] Annulation of N-(1-Naphthyl)acetamide with Two Alkynoates via Cleavage of Adjacent C–H and C–N Bonds Catalyzed by an Electron-Deficient Rhodium(III) Complex
por: Terasawa, Jyunichi, et al.
Publicado: (2018)

Practical synthesis of isocoumarins via Rh(III)-catalyzed C–H activation/annulation cascade
por: Gao, Qian-Ci, et al.
Publicado: (2023)

Nickel-catalyzed oxidative C–H/N–H annulation of N-heteroaromatic compounds with alkynes
por: Obata, Atsushi, et al.
Publicado: (2019)

Electrooxidation enables highly regioselective dearomative annulation of indole and benzofuran derivatives
por: Liu, Kun, et al.
Publicado: (2020)

Nickel-catalyzed C–O/N–H, C–S/N–H, and C–CN/N–H annulation of aromatic amides with alkynes: C–O, C–S, and C–CN activation
por: Iyori, Yasuaki, et al.
Publicado: (2020)

Electrochemical C−H Amidation of Heteroarenes with N‐Alkyl Sulfonamides in Aqueous Medium
por: Zhang, Yan, et al.
Publicado: (2020)

Merging rhodium-catalysed C–H activation and hydroamination in a highly selective [4+2] imine/alkyne annulation
por: Manan, Rajith S., et al.
Publicado: (2016)

Rhodium-catalyzed C–H functionalization-based approach to eight-membered lactams
por: Wu, Shangze, et al.
Publicado: (2015)

Catalyst Deactivation During Rhodium Complex‐Catalyzed Propargylic C−H Activation
por: Möller, Saskia, et al.
Publicado: (2021)

Directing group assisted rhodium catalyzed meta-C–H alkynylation of arenes
por: Sasmal, Sheuli, et al.
Publicado: (2022)

Rhodium‐Catalyzed C−H Methylation and Alkylation Reactions by Carbene‐Transfer Reactions
por: Empel, Claire, et al.
Publicado: (2022)

Rhodium‐NHC‐Catalyzed gem‐Specific O‐Selective Hydropyridonation of Terminal Alkynes
por: Galiana‐Cameo, María, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_i2j3uocjq1f3irem42e4vodqmf