Photocatalyzed Transition‐Metal‐Free Oxidative Cross‐Coupling Reactions of Tetraorganoborates

Readily accessible tetraorganoborate salts undergo selective coupling reactions under blue light irradiation in the presence of catalytic amounts of transition‐metal‐free acridinium photocatalysts to furnish unsymmetrical biaryls, heterobiaryls and arylated olefins. This represents an interesting co...

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Autores principales: Music, Arif, Baumann, Andreas N., Boser, Florian, Müller, Nicolas, Matz, Florian, Jagau, Thomas C., Didier, Dorian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986674/
https://www.ncbi.nlm.nih.gov/pubmed/33306228
http://dx.doi.org/10.1002/chem.202005282
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author Music, Arif
Baumann, Andreas N.
Boser, Florian
Müller, Nicolas
Matz, Florian
Jagau, Thomas C.
Didier, Dorian
author_facet Music, Arif
Baumann, Andreas N.
Boser, Florian
Müller, Nicolas
Matz, Florian
Jagau, Thomas C.
Didier, Dorian
author_sort Music, Arif
collection PubMed
description Readily accessible tetraorganoborate salts undergo selective coupling reactions under blue light irradiation in the presence of catalytic amounts of transition‐metal‐free acridinium photocatalysts to furnish unsymmetrical biaryls, heterobiaryls and arylated olefins. This represents an interesting conceptual approach to forge C−C bonds between aryl, heteroaryl and alkenyl groups under smooth photochemical conditions. Computational studies were conducted to investigate the mechanism of the transformation.
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spelling pubmed-79866742021-03-25 Photocatalyzed Transition‐Metal‐Free Oxidative Cross‐Coupling Reactions of Tetraorganoborates Music, Arif Baumann, Andreas N. Boser, Florian Müller, Nicolas Matz, Florian Jagau, Thomas C. Didier, Dorian Chemistry Communications Readily accessible tetraorganoborate salts undergo selective coupling reactions under blue light irradiation in the presence of catalytic amounts of transition‐metal‐free acridinium photocatalysts to furnish unsymmetrical biaryls, heterobiaryls and arylated olefins. This represents an interesting conceptual approach to forge C−C bonds between aryl, heteroaryl and alkenyl groups under smooth photochemical conditions. Computational studies were conducted to investigate the mechanism of the transformation. John Wiley and Sons Inc. 2021-02-03 2021-03-01 /pmc/articles/PMC7986674/ /pubmed/33306228 http://dx.doi.org/10.1002/chem.202005282 Text en © 2020 The Authors. Published by Wiley-VCH GmbH This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Music, Arif
Baumann, Andreas N.
Boser, Florian
Müller, Nicolas
Matz, Florian
Jagau, Thomas C.
Didier, Dorian
Photocatalyzed Transition‐Metal‐Free Oxidative Cross‐Coupling Reactions of Tetraorganoborates
title Photocatalyzed Transition‐Metal‐Free Oxidative Cross‐Coupling Reactions of Tetraorganoborates
title_full Photocatalyzed Transition‐Metal‐Free Oxidative Cross‐Coupling Reactions of Tetraorganoborates
title_fullStr Photocatalyzed Transition‐Metal‐Free Oxidative Cross‐Coupling Reactions of Tetraorganoborates
title_full_unstemmed Photocatalyzed Transition‐Metal‐Free Oxidative Cross‐Coupling Reactions of Tetraorganoborates
title_short Photocatalyzed Transition‐Metal‐Free Oxidative Cross‐Coupling Reactions of Tetraorganoborates
title_sort photocatalyzed transition‐metal‐free oxidative cross‐coupling reactions of tetraorganoborates
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986674/
https://www.ncbi.nlm.nih.gov/pubmed/33306228
http://dx.doi.org/10.1002/chem.202005282
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