Cargando…

PQQ‐dependent Dehydrogenase Enables One‐pot Bi‐enzymatic Enantio‐convergent Biocatalytic Amination of Racemic sec‐Allylic Alcohols

The asymmetric amination of secondary racemic allylic alcohols bears several challenges like the reactivity of the bi‐functional substrate/product as well as of the α,β‐unsaturated ketone intermediate in an oxidation‐reductive amination sequence. Heading for a biocatalytic amination cascade with a m...

Descripción completa

Detalles Bibliográficos
Autores principales:	Gandomkar, Somayyeh, Rocha, Raquel, Sorgenfrei, Frieda A., Montero, Lía Martínez, Fuchs, Michael, Kroutil, Wolfgang
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986696/ https://www.ncbi.nlm.nih.gov/pubmed/33777250 http://dx.doi.org/10.1002/cctc.202001707

Ejemplares similares

Biocatalytic Enantioselective Oxidation of Sec‐Allylic Alcohols with Flavin‐Dependent Oxidases
por: Gandomkar, Somayyeh, et al.
Publicado: (2019)

Extending Designed Linear Biocatalytic Cascades for Organic Synthesis
por: Gandomkar, Somayyeh, et al.
Publicado: (2018)

Enantio and Diastereoselective Addition of Phenylacetylene to Racemic α-chloroketones
por: Alesi, Silvia, et al.
Publicado: (2011)

Enantio‐ and Diastereoselective Suzuki–Miyaura Coupling with Racemic Bicycles
por: Goetzke, F. Wieland, et al.
Publicado: (2019)

Enantio‐ and Diastereoselective Copper‐Catalyzed Allylboration of Alkynes with Allylic gem‐Dichlorides
por: Chaves‐Pouso, Andrea, et al.
Publicado: (2022)

Transmembrane Shuttling of Photosynthetically Produced Electrons to Propel Extracellular Biocatalytic Redox Reactions in a Modular Fashion
por: Jurkaš, Valentina, et al.
Publicado: (2022)

Counterion-Enhanced Pd/Enamine Catalysis: Direct Asymmetric α-Allylation of Aldehydes with Allylic Alcohols by Chiral Amines and Achiral or Racemic Phosphoric Acids
por: Pálvölgyi, Ádám Márk, et al.
Publicado: (2020)

Synthesis of Atropisomeric Hydrazides by One‐Pot Sequential Enantio‐ and Diastereoselective Catalysis
por: Portolani, Chiara, et al.
Publicado: (2022)

Enantio- and Z-selective synthesis of functionalized alkenes bearing tertiary allylic stereogenic center
por: Ge, Luo, et al.
Publicado: (2023)

Deracemization of a Racemic Allylic Sulfoxide Using Viedma Ripening
por: Engwerda, Anthonius H. J., et al.
Publicado: (2017)

One‐Pot Synthesis of Chiral N‐Arylamines by Combining Biocatalytic Aminations with Buchwald–Hartwig N‐Arylation
por: Cosgrove, Sebastian C., et al.
Publicado: (2020)

Biocatalytic characterization of an alcohol dehydrogenase variant deduced from Lactobacillus kefir in asymmetric hydrogen transfer
por: Rudzka, Aleksandra, et al.
Publicado: (2023)

Highly Enantioselective Hiyama Cross-Coupling via Rh-Catalyzed Allylic Arylation of Racemic Allyl Chlorides
por: González, Jesús, et al.
Publicado: (2019)

Spiro-fused carbohydrate oxazoline ligands: Synthesis and application as enantio-discrimination agents in asymmetric allylic alkylation
por: Kraft, Jochen, et al.
Publicado: (2016)

The Industrial Age of Biocatalytic Transamination
por: Fuchs, Michael, et al.
Publicado: (2015)

Asymmetric Preparation of prim-, sec-, and tert-Amines Employing Selected Biocatalysts
por: Kroutil, Wolfgang, et al.
Publicado: (2013)

Copper-catalyzed asymmetric allylic alkylation of racemic inert cyclic allylic ethers under batch and flow conditions
por: Li, Jun, et al.
Publicado: (2023)

From Racemic Alcohols to Enantiopure Amines: Ru-Catalyzed Diastereoselective Amination
por: Oldenhuis, Nathan J., et al.
Publicado: (2014)

Enantio- and regioselective asymmetric allylic substitution using a chiral aminophosphinite ruthenium complex: an experimental and theoretical investigation
por: Jena, Rajesh K., et al.
Publicado: (2021)

Biocatalytic trifluoromethylation of unprotected phenols
por: Simon, Robert C., et al.
Publicado: (2016)

Biocatalytic Oxidative Cascade for the Conversion of Fatty Acids into α‐Ketoacids via Internal H(2)O(2) Recycling
por: Gandomkar, Somayyeh, et al.
Publicado: (2017)

Recent biocatalytic oxidation–reduction cascades
por: Schrittwieser, Joerg H, et al.
Publicado: (2011)

Enantioselective construction of C-chiral allylic sulfilimines via the iridium-catalyzed allylic amination with S,S-diphenylsulfilimine: asymmetric synthesis of primary allylic amines
por: Grange, Rebecca L., et al.
Publicado: (2015)

Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
por: Schäfer, Philipp, et al.
Publicado: (2017)

Kinetic Resolution of Racemic Primary Amines Using Geobacillus stearothermophilus Amine Dehydrogenase Variant
por: Tseliou, Vasilis, et al.
Publicado: (2020)

Sustainable Asymmetric Organolithium Chemistry: Enantio‐ and Chemoselective Acylations through Recycling of Solvent, Sparteine, and Weinreb “Amine”
por: Monticelli, Serena, et al.
Publicado: (2019)

Enantio‐ and Diastereoselective Synthesis of Homopropargyl Amines by Copper‐Catalyzed Coupling of Imines, 1,3‐Enynes, and Diborons
por: Manna, Srimanta, et al.
Publicado: (2020)

One-pot synthesis of enantiomerically pure N-protected allylic amines from N-protected α-amino esters
por: Silveira-Dorta, Gastón, et al.
Publicado: (2016)

Biocatalytic Friedel–Crafts Acylation and Fries Reaction
por: Schmidt, Nina G., et al.
Publicado: (2017)

A Biocatalytic Platform for the Synthesis of Enantiopure Propargylic Alcohols and Amines
por: Sang, Xianke, et al.
Publicado: (2022)

Screening primary racemic amines for enantioseparation by derivatized polysaccharide and cyclofructan columns()
por: Lim, Yeeun, et al.
Publicado: (2016)

Thiols Act as Methyl Traps in the Biocatalytic Demethylation of Guaiacol Derivatives
por: Pompei, Simona, et al.
Publicado: (2021)

Enantio-sensitive unidirectional light bending
por: Ayuso, David, et al.
Publicado: (2021)

Application of Polysaccharide-Based Chiral High-Performance Liquid Chromatography Columns for the Separation of Regio-, E/Z-, and Enantio–Isomeric Mixtures of Allylic Compounds
por: Ohji, Takehito, et al.
Publicado: (2022)

Enantio‐ and Regioconvergent Nickel‐Catalyzed C(sp(3))−C(sp(3)) Cross‐Coupling of Allylic Electrophiles Steered by a Silyl Group
por: Kranidiotis‐Hisatomi, Nektarios, et al.
Publicado: (2021)

Regioselective Biocatalytic C4‐Prenylation of Unprotected Tryptophan Derivatives
por: Eggbauer, Bettina, et al.
Publicado: (2022)

Building Bridges: Biocatalytic C–C-Bond Formation toward Multifunctional Products
por: Schmidt, Nina G., et al.
Publicado: (2016)

One-Pot Biocatalytic Synthesis of Primary, Secondary, and Tertiary Amines with Two Stereocenters from α,β-Unsaturated Ketones Using Alkyl-Ammonium Formate
por: Knaus, Tanja, et al.
Publicado: (2022)

Copper-catalysed asymmetric allylic alkylation of alkylzirconocenes to racemic 3,6-dihydro-2H-pyrans
por: Rideau, Emeline, et al.
Publicado: (2015)

Author Correction: Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
por: Schäfer, Philipp, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_t3brssn0d1oj9a6ucnhnoup5ij