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Structural and Oxidation State Alternatives in Platinum and Palladium Complexes of a Redox‐Active Amidinato Ligand

Reaction of [Pt(DMSO)(2)Cl(2)] or [Pd(MeCN)(2)Cl(2)] with the electron‐rich LH=N,N’‐bis(4‐dimethylaminophenyl)ethanimidamide yielded mononuclear [PtL(2)] (1) but dinuclear [Pd(2)L(4)] (2), a paddle‐wheel complex. The neutral compounds were characterized through experiments (crystal structures, elect...

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Detalles Bibliográficos
Autores principales:	Ehret, Fabian, Filippou, Vasileios, Blickle, Svenja, Bubrin, Martina, Záliš, Stanislav, Kaim, Wolfgang
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986709/ https://www.ncbi.nlm.nih.gov/pubmed/32959415 http://dx.doi.org/10.1002/chem.202003636

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