Bulky Polyfluorinated Terphenyldiphenylboranes: Water Tolerant Lewis Acids

Protocols for the synthesis of the bulky polyfluorinated triarylboranes 2,6‐(C(6)F(5))(2)C(6)F(3)B(C(6)F(5))(2) (1), 2,6‐(C(6)F(5))(2)C(6)F(3)B[3,5‐(CF(3))(2)C(6)H(3)] (2), 2,4,6‐(C(6)F(5))(3)C(6)H(2)B(C(6)F(5))(2) (3), 2,4,6‐(C(6)F(5))(3)C(6)H(2)B[3,5‐(CF(3))(2)C(6)H(3)] (4) were developed. All bor...

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Autores principales: Stoian, Corina, Olaru, Marian, Cucuiet, Teodor A., Kegyes, Krisztina T., Sava, Alexandru, Timoshkin, Alexey Y., Raţ, Ciprian I., Beckmann, Jens
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986919/
https://www.ncbi.nlm.nih.gov/pubmed/33368648
http://dx.doi.org/10.1002/chem.202005367
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author Stoian, Corina
Olaru, Marian
Cucuiet, Teodor A.
Kegyes, Krisztina T.
Sava, Alexandru
Timoshkin, Alexey Y.
Raţ, Ciprian I.
Beckmann, Jens
author_facet Stoian, Corina
Olaru, Marian
Cucuiet, Teodor A.
Kegyes, Krisztina T.
Sava, Alexandru
Timoshkin, Alexey Y.
Raţ, Ciprian I.
Beckmann, Jens
author_sort Stoian, Corina
collection PubMed
description Protocols for the synthesis of the bulky polyfluorinated triarylboranes 2,6‐(C(6)F(5))(2)C(6)F(3)B(C(6)F(5))(2) (1), 2,6‐(C(6)F(5))(2)C(6)F(3)B[3,5‐(CF(3))(2)C(6)H(3)] (2), 2,4,6‐(C(6)F(5))(3)C(6)H(2)B(C(6)F(5))(2) (3), 2,4,6‐(C(6)F(5))(3)C(6)H(2)B[3,5‐(CF(3))(2)C(6)H(3)] (4) were developed. All boranes are water tolerant and according to the Gutmann‐Beckett method, 1–3 display Lewis acidities larger than that of the prominent B(C(6)F(5))(3).
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spelling pubmed-79869192021-03-25 Bulky Polyfluorinated Terphenyldiphenylboranes: Water Tolerant Lewis Acids Stoian, Corina Olaru, Marian Cucuiet, Teodor A. Kegyes, Krisztina T. Sava, Alexandru Timoshkin, Alexey Y. Raţ, Ciprian I. Beckmann, Jens Chemistry Communications Protocols for the synthesis of the bulky polyfluorinated triarylboranes 2,6‐(C(6)F(5))(2)C(6)F(3)B(C(6)F(5))(2) (1), 2,6‐(C(6)F(5))(2)C(6)F(3)B[3,5‐(CF(3))(2)C(6)H(3)] (2), 2,4,6‐(C(6)F(5))(3)C(6)H(2)B(C(6)F(5))(2) (3), 2,4,6‐(C(6)F(5))(3)C(6)H(2)B[3,5‐(CF(3))(2)C(6)H(3)] (4) were developed. All boranes are water tolerant and according to the Gutmann‐Beckett method, 1–3 display Lewis acidities larger than that of the prominent B(C(6)F(5))(3). John Wiley and Sons Inc. 2021-02-03 2021-03-01 /pmc/articles/PMC7986919/ /pubmed/33368648 http://dx.doi.org/10.1002/chem.202005367 Text en © 2020 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Stoian, Corina
Olaru, Marian
Cucuiet, Teodor A.
Kegyes, Krisztina T.
Sava, Alexandru
Timoshkin, Alexey Y.
Raţ, Ciprian I.
Beckmann, Jens
Bulky Polyfluorinated Terphenyldiphenylboranes: Water Tolerant Lewis Acids
title Bulky Polyfluorinated Terphenyldiphenylboranes: Water Tolerant Lewis Acids
title_full Bulky Polyfluorinated Terphenyldiphenylboranes: Water Tolerant Lewis Acids
title_fullStr Bulky Polyfluorinated Terphenyldiphenylboranes: Water Tolerant Lewis Acids
title_full_unstemmed Bulky Polyfluorinated Terphenyldiphenylboranes: Water Tolerant Lewis Acids
title_short Bulky Polyfluorinated Terphenyldiphenylboranes: Water Tolerant Lewis Acids
title_sort bulky polyfluorinated terphenyldiphenylboranes: water tolerant lewis acids
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986919/
https://www.ncbi.nlm.nih.gov/pubmed/33368648
http://dx.doi.org/10.1002/chem.202005367
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