N,N‐Dialkylhydrazones as Versatile Umpolung Reagents in Enantioselective Anion‐Binding Catalysis

An enantioselective anion‐binding organocatalytic approach with versatile N,N‐dialkylhydrazones (DAHs) as polarity‐reversed (umpolung) nucleophiles is presented. For the application of this concept, a highly ordered hydrogen‐bond (HB) network between a carefully selected CF(3)‐substituted triazole‐b...

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Detalles Bibliográficos
Autores principales: Gómez‐Martínez, Melania, del Carmen Pérez‐Aguilar, María, Piekarski, Dariusz G., Daniliuc, Constantin G., García Mancheño, Olga
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986925/
https://www.ncbi.nlm.nih.gov/pubmed/33306858
http://dx.doi.org/10.1002/anie.202013380

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986925/
https://www.ncbi.nlm.nih.gov/pubmed/33306858
http://dx.doi.org/10.1002/anie.202013380

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