Controllable Synthesis of Bimetallic Nanostructures Using Biogenic Reagents: A Green Perspective

[Image: see text] Bimetallic nanostructures are emerging as a significant class of metal nanomaterials due to their exceptional properties that are useful in various areas of science and technology. When used for catalysis and sensing applications, bimetallic nanostructures have been noted to exhibit better performance relative to their monometallic counterparts owing to synergistic effects. Furthermore, their dual metal composition and configuration can be modulated to achieve optimal activity for the desired functions. However, as with other nanostructured metals, bimetallic nanostructures are usually prepared through wet chemical routes that involve the use of harsh reducing agents and hazardous stabilizing agents. In response to intensifying concerns over the toxicity of chemicals used in nanomaterial synthesis, the scientific community has increasingly turned its attention toward environmentally and biologically compatible reagents that can enable green and sustainable nanofabrication processes. This article aims to provide an evaluation of the green synthetic methods of constructing bimetallic nanostructures, with emphasis on the use of biogenic resources (e.g., plant extracts, DNA, proteins) as safe and practical reagents. Special attention is devoted to biogenic synthetic protocols that demonstrate controllable nanoscale features, such as size, composition, morphology, and configuration. The potential use of these biogenically prepared bimetallic nanostructures as catalysts and sensors is also discussed. It is hoped that this article will serve as a valuable reference on bimetallic nanostructures and will help fuel new ideas for the development of more eco-friendly strategies for the controllable synthesis of various types of nanostructured bimetallic systems.