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Rh–Sb Nanoclusters: Synthesis, Structure, and Electrochemical Studies of the Atomically Precise [Rh(20)Sb(3)(CO)(36)](3–) and [Rh(21)Sb(2)(CO)(38)](5–) Carbonyl Compounds
[Image: see text] The reactivity of [Rh(7)(CO)(16)](3–) with SbCl(3) has been deeply investigated with the aim of finding a new approach to prepare atomically precise metalloid clusters. In particular, by varying the stoichiometric ratios, the reaction atmosphere (carbon monoxide or nitrogen), the s...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7997401/ https://www.ncbi.nlm.nih.gov/pubmed/32207932 http://dx.doi.org/10.1021/acs.inorgchem.9b03135 |