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A Polymer Blend Electrolyte Based on CS with Enhanced Ion Transport and Electrochemical Properties for Electrical Double Layer Capacitor Applications

The fabrication of energy storage EDLC in this work is achieved with the implementation of a conducting chitosan–methylcellulose–NH(4)NO(3)–glycerol polymer electrolyte system. The simple solution cast method has been used to prepare the electrolyte. The impedance of the samples was fitted with equi...

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Autores principales: Aziz, Shujahadeen B., Dannoun, Elham M. A., Hamsan, Muhamad H., Ghareeb, Hewa O., Nofal, Muaffaq M., Karim, Wrya O., Asnawi, Ahmad S. F. M., Hadi, Jihad M., Kadir, Mohd Fakhrul Zamani Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8002724/
https://www.ncbi.nlm.nih.gov/pubmed/33803001
http://dx.doi.org/10.3390/polym13060930
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author Aziz, Shujahadeen B.
Dannoun, Elham M. A.
Hamsan, Muhamad H.
Ghareeb, Hewa O.
Nofal, Muaffaq M.
Karim, Wrya O.
Asnawi, Ahmad S. F. M.
Hadi, Jihad M.
Kadir, Mohd Fakhrul Zamani Abdul
author_facet Aziz, Shujahadeen B.
Dannoun, Elham M. A.
Hamsan, Muhamad H.
Ghareeb, Hewa O.
Nofal, Muaffaq M.
Karim, Wrya O.
Asnawi, Ahmad S. F. M.
Hadi, Jihad M.
Kadir, Mohd Fakhrul Zamani Abdul
author_sort Aziz, Shujahadeen B.
collection PubMed
description The fabrication of energy storage EDLC in this work is achieved with the implementation of a conducting chitosan–methylcellulose–NH(4)NO(3)–glycerol polymer electrolyte system. The simple solution cast method has been used to prepare the electrolyte. The impedance of the samples was fitted with equivalent circuits to design the circuit diagram. The parameters associated with ion transport are well studied at various plasticizer concentrations. The FTIR investigation has been done on the films to detect the interaction that occurs among plasticizer and polymer electrolyte. To get more insights into ion transport parameters, the FTIR was deconvoluted. The transport properties achieved from both impedance and FTIR are discussed in detail. It was discovered that the transport parameter findings are in good agreement with both impedance and FTIR studies. A sample with high transport properties was characterized for ion dominancy and stability through the TNM and LSV investigations. The dominancy of ions in the electrolyte verified as the t(ion) of the electrolyte is established to be 0.933 whereas it is potentially stable up to 1.87 V. The rechargeability of the EDLC is steady up to 500 cycles. The internal resistance, energy density, and power density of the EDLC at the 1st cycle are 53 ohms, 6.97 Wh/kg, and 1941 W/kg, respectively.
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spelling pubmed-80027242021-03-28 A Polymer Blend Electrolyte Based on CS with Enhanced Ion Transport and Electrochemical Properties for Electrical Double Layer Capacitor Applications Aziz, Shujahadeen B. Dannoun, Elham M. A. Hamsan, Muhamad H. Ghareeb, Hewa O. Nofal, Muaffaq M. Karim, Wrya O. Asnawi, Ahmad S. F. M. Hadi, Jihad M. Kadir, Mohd Fakhrul Zamani Abdul Polymers (Basel) Article The fabrication of energy storage EDLC in this work is achieved with the implementation of a conducting chitosan–methylcellulose–NH(4)NO(3)–glycerol polymer electrolyte system. The simple solution cast method has been used to prepare the electrolyte. The impedance of the samples was fitted with equivalent circuits to design the circuit diagram. The parameters associated with ion transport are well studied at various plasticizer concentrations. The FTIR investigation has been done on the films to detect the interaction that occurs among plasticizer and polymer electrolyte. To get more insights into ion transport parameters, the FTIR was deconvoluted. The transport properties achieved from both impedance and FTIR are discussed in detail. It was discovered that the transport parameter findings are in good agreement with both impedance and FTIR studies. A sample with high transport properties was characterized for ion dominancy and stability through the TNM and LSV investigations. The dominancy of ions in the electrolyte verified as the t(ion) of the electrolyte is established to be 0.933 whereas it is potentially stable up to 1.87 V. The rechargeability of the EDLC is steady up to 500 cycles. The internal resistance, energy density, and power density of the EDLC at the 1st cycle are 53 ohms, 6.97 Wh/kg, and 1941 W/kg, respectively. MDPI 2021-03-17 /pmc/articles/PMC8002724/ /pubmed/33803001 http://dx.doi.org/10.3390/polym13060930 Text en © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Aziz, Shujahadeen B.
Dannoun, Elham M. A.
Hamsan, Muhamad H.
Ghareeb, Hewa O.
Nofal, Muaffaq M.
Karim, Wrya O.
Asnawi, Ahmad S. F. M.
Hadi, Jihad M.
Kadir, Mohd Fakhrul Zamani Abdul
A Polymer Blend Electrolyte Based on CS with Enhanced Ion Transport and Electrochemical Properties for Electrical Double Layer Capacitor Applications
title A Polymer Blend Electrolyte Based on CS with Enhanced Ion Transport and Electrochemical Properties for Electrical Double Layer Capacitor Applications
title_full A Polymer Blend Electrolyte Based on CS with Enhanced Ion Transport and Electrochemical Properties for Electrical Double Layer Capacitor Applications
title_fullStr A Polymer Blend Electrolyte Based on CS with Enhanced Ion Transport and Electrochemical Properties for Electrical Double Layer Capacitor Applications
title_full_unstemmed A Polymer Blend Electrolyte Based on CS with Enhanced Ion Transport and Electrochemical Properties for Electrical Double Layer Capacitor Applications
title_short A Polymer Blend Electrolyte Based on CS with Enhanced Ion Transport and Electrochemical Properties for Electrical Double Layer Capacitor Applications
title_sort polymer blend electrolyte based on cs with enhanced ion transport and electrochemical properties for electrical double layer capacitor applications
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8002724/
https://www.ncbi.nlm.nih.gov/pubmed/33803001
http://dx.doi.org/10.3390/polym13060930
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