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Phase Behavior of Aqueous Biphasic Systems with Choline Alkanoate Ionic Liquids and Phosphate Solutions: The Influence of pH

Aqueous biphasic systems (ABS) composed of the choline alkanoate ionic liquids (ILs) choline acetate [Cho][OAc], choline propanoate [Cho][Pro], choline butyrate [Cho][But], and choline hexanoate [Cho][Hex], mixed with K(3)PO(4) solutions at pH 7.2 and 14.5, were prepared and their phase diagrams wer...

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Detalles Bibliográficos
Autores principales: Berton, Paula, Tian, Hongzhe, Rogers, Robin D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8003127/
https://www.ncbi.nlm.nih.gov/pubmed/33803761
http://dx.doi.org/10.3390/molecules26061702
Descripción
Sumario:Aqueous biphasic systems (ABS) composed of the choline alkanoate ionic liquids (ILs) choline acetate [Cho][OAc], choline propanoate [Cho][Pro], choline butyrate [Cho][But], and choline hexanoate [Cho][Hex], mixed with K(3)PO(4) solutions at pH 7.2 and 14.5, were prepared and their phase diagrams were compared. The ability to form ABS with alkaline K(3)PO(4) solutions decreased in the order [Cho][OAc] ≈ [Cho][Pro] > [Cho][But] > [Cho][Hex], while with neutral K(3)PO(4) solutions, [Cho][OAc] could not form an ABS, and the other three ILs performed similarly. All of the biphasic regions of the ABS decreased with the increase in pH. (1)H-NMR data indicated anion exchange between phases in ABS at neutral pH. The ABS at neutral pH were evaluated to extract the triazine herbicides simazine, cyanazine, and atrazine, and the ABS formed by [Cho][Pro] and the pH 7.2 K(3)PO(4) solution has shown extraction recoveries higher than 90%.