Chemical Adsorption Strategy for DMC-MeOH Mixture Separation †

The effective separation of dimethyl carbonate (DMC) from its methanol mixture through simple, inexpensive and low energy-input method is a promising and challenging field in the process of organic synthesis. Herein, a reversible adsorption strategy through the assistance of superbase and CO(2) for...

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Detalles Bibliográficos
Autores principales: Zhang, Fucan, Liu, Ping, Zhang, Kan, Song, Qing-Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8003759/
https://www.ncbi.nlm.nih.gov/pubmed/33808850
http://dx.doi.org/10.3390/molecules26061735
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author Zhang, Fucan
Liu, Ping
Zhang, Kan
Song, Qing-Wen
author_facet Zhang, Fucan
Liu, Ping
Zhang, Kan
Song, Qing-Wen
author_sort Zhang, Fucan
collection PubMed
description The effective separation of dimethyl carbonate (DMC) from its methanol mixture through simple, inexpensive and low energy-input method is a promising and challenging field in the process of organic synthesis. Herein, a reversible adsorption strategy through the assistance of superbase and CO(2) for DMC/methanol separation at ambient condition was described. The process was demonstrated effectively via the excellent CO(2) adsorption efficiency. Notably, the protocol was also suitable to other alcohol (i.e., monohydric alcohol, dihydric alcohol, trihydric alcohol) mixtures. The study provided guidance for potential separation of DMC/alcohol mixture in the scale-up production.
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spelling pubmed-80037592021-03-28 Chemical Adsorption Strategy for DMC-MeOH Mixture Separation † Zhang, Fucan Liu, Ping Zhang, Kan Song, Qing-Wen Molecules Communication The effective separation of dimethyl carbonate (DMC) from its methanol mixture through simple, inexpensive and low energy-input method is a promising and challenging field in the process of organic synthesis. Herein, a reversible adsorption strategy through the assistance of superbase and CO(2) for DMC/methanol separation at ambient condition was described. The process was demonstrated effectively via the excellent CO(2) adsorption efficiency. Notably, the protocol was also suitable to other alcohol (i.e., monohydric alcohol, dihydric alcohol, trihydric alcohol) mixtures. The study provided guidance for potential separation of DMC/alcohol mixture in the scale-up production. MDPI 2021-03-19 /pmc/articles/PMC8003759/ /pubmed/33808850 http://dx.doi.org/10.3390/molecules26061735 Text en © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Zhang, Fucan
Liu, Ping
Zhang, Kan
Song, Qing-Wen
Chemical Adsorption Strategy for DMC-MeOH Mixture Separation †
title Chemical Adsorption Strategy for DMC-MeOH Mixture Separation †
title_full Chemical Adsorption Strategy for DMC-MeOH Mixture Separation †
title_fullStr Chemical Adsorption Strategy for DMC-MeOH Mixture Separation †
title_full_unstemmed Chemical Adsorption Strategy for DMC-MeOH Mixture Separation †
title_short Chemical Adsorption Strategy for DMC-MeOH Mixture Separation †
title_sort chemical adsorption strategy for dmc-meoh mixture separation †
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8003759/
https://www.ncbi.nlm.nih.gov/pubmed/33808850
http://dx.doi.org/10.3390/molecules26061735
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AT liuping chemicaladsorptionstrategyfordmcmeohmixtureseparation
AT zhangkan chemicaladsorptionstrategyfordmcmeohmixtureseparation
AT songqingwen chemicaladsorptionstrategyfordmcmeohmixtureseparation

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