Visible-Light Photoredox-Catalyzed Amidation of Benzylic Alcohols

[Image: see text] A new photocatalyzed route to amides from alcohols and amines mediated by visible light is presented. The reaction is carried out in ethyl acetate as a solvent. Ethyl acetate can be defined a green and bio-based solvent. The starting materials such as the energy source are easily a...

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Detalles Bibliográficos
Autores principales: Gaspa, Silvia, Farina, Andrea, Tilocca, Mariella, Porcheddu, Andrea, Pisano, Luisa, Carraro, Massimo, Azzena, Ugo, De Luca, Lidia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8009506/
https://www.ncbi.nlm.nih.gov/pubmed/32662268
http://dx.doi.org/10.1021/acs.joc.0c01320
Descripción
Sumario:[Image: see text] A new photocatalyzed route to amides from alcohols and amines mediated by visible light is presented. The reaction is carried out in ethyl acetate as a solvent. Ethyl acetate can be defined a green and bio-based solvent. The starting materials such as the energy source are easily available, stable, and inexpensive. The reaction has shown to be general and high yielding.

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