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Molecular Catalysts with Intramolecular Re–O Bond for Electrochemical Reduction of Carbon Dioxide

[Image: see text] A new Re bipyridine-type complex, namely, fac-Re(pmbpy)(CO)(3)Cl (pmbpy = 4-phenyl-6-(2-hydroxy-phenyl)-2,2′-bipyridine), 1, carrying a single OH moiety as local proton source, has been synthesized, and its electrochemical behavior under Ar and under CO(2) has been characterized. T...

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Detalles Bibliográficos
Autores principales: Rotundo, Laura, Polyansky, Dmitry E., Gobetto, Roberto, Grills, David C., Fujita, Etsuko, Nervi, Carlo, Manbeck, Gerald F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8009525/
https://www.ncbi.nlm.nih.gov/pubmed/32804491
http://dx.doi.org/10.1021/acs.inorgchem.0c01181