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Orthogonal Syntheses of 3.2.0 Bicycles from Enallenes Promoted by Visible Light

[Image: see text] Enallenes can be readily converted into two families of 3.2.0 (hetero)bicycles with high diastereoselectivities through the combination of visible light with a suitable Ir(III) complex (1 mol %). Two complementary pathways, namely, a photocycloaddition versus a radical chain, can t...

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Detalles Bibliográficos
Autores principales: Serafino, Andrea, Balestri, Davide, Marchiò, Luciano, Malacria, Max, Derat, Etienne, Maestri, Giovanni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8010793/
https://www.ncbi.nlm.nih.gov/pubmed/32806183
http://dx.doi.org/10.1021/acs.orglett.0c02193