Dyedauxiliary Groups, an Emerging Approach in Organic Chemistry. The Case of Arylazo Sulfones

[Image: see text] The number of research papers that report photocatalyst-free protocols is currently increasing. Among the different approaches proposed, the conversion of a strong C–X bond of a stable substrate into a photolabile reactive moiety has been recently proposed. In this Synopsis, we int...

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Autores principales: Qiu, Di, Lian, Chang, Mao, Jinshan, Fagnoni, Maurizio, Protti, Stefano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8011925/
https://www.ncbi.nlm.nih.gov/pubmed/32956584
http://dx.doi.org/10.1021/acs.joc.0c01895
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author Qiu, Di
Lian, Chang
Mao, Jinshan
Fagnoni, Maurizio
Protti, Stefano
author_facet Qiu, Di
Lian, Chang
Mao, Jinshan
Fagnoni, Maurizio
Protti, Stefano
author_sort Qiu, Di
collection PubMed
description [Image: see text] The number of research papers that report photocatalyst-free protocols is currently increasing. Among the different approaches proposed, the conversion of a strong C–X bond of a stable substrate into a photolabile reactive moiety has been recently proposed. In this Synopsis, we introduce the so-dubbed dyedauxiliary group strategy by focusing on arylazo sulfones that are bench stable and visible-light responsive derivatives of anilines that have been exploited as precursors of a wide range of intermediates, including carbon-centered radicals as well as aryl cations.
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spelling pubmed-80119252021-04-02 Dyedauxiliary Groups, an Emerging Approach in Organic Chemistry. The Case of Arylazo Sulfones Qiu, Di Lian, Chang Mao, Jinshan Fagnoni, Maurizio Protti, Stefano J Org Chem [Image: see text] The number of research papers that report photocatalyst-free protocols is currently increasing. Among the different approaches proposed, the conversion of a strong C–X bond of a stable substrate into a photolabile reactive moiety has been recently proposed. In this Synopsis, we introduce the so-dubbed dyedauxiliary group strategy by focusing on arylazo sulfones that are bench stable and visible-light responsive derivatives of anilines that have been exploited as precursors of a wide range of intermediates, including carbon-centered radicals as well as aryl cations. American Chemical Society 2020-09-21 2020-10-16 /pmc/articles/PMC8011925/ /pubmed/32956584 http://dx.doi.org/10.1021/acs.joc.0c01895 Text en Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Qiu, Di
Lian, Chang
Mao, Jinshan
Fagnoni, Maurizio
Protti, Stefano
Dyedauxiliary Groups, an Emerging Approach in Organic Chemistry. The Case of Arylazo Sulfones
title Dyedauxiliary Groups, an Emerging Approach in Organic Chemistry. The Case of Arylazo Sulfones
title_full Dyedauxiliary Groups, an Emerging Approach in Organic Chemistry. The Case of Arylazo Sulfones
title_fullStr Dyedauxiliary Groups, an Emerging Approach in Organic Chemistry. The Case of Arylazo Sulfones
title_full_unstemmed Dyedauxiliary Groups, an Emerging Approach in Organic Chemistry. The Case of Arylazo Sulfones
title_short Dyedauxiliary Groups, an Emerging Approach in Organic Chemistry. The Case of Arylazo Sulfones
title_sort dyedauxiliary groups, an emerging approach in organic chemistry. the case of arylazo sulfones
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8011925/
https://www.ncbi.nlm.nih.gov/pubmed/32956584
http://dx.doi.org/10.1021/acs.joc.0c01895
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