Chemoselective Homologation–Deoxygenation Strategy Enabling the Direct Conversion of Carbonyls into (n+1)-Halomethyl-Alkanes

[Image: see text] The sequential installation of a carbenoid and a hydride into a carbonyl, furnishing halomethyl alkyl derivatives, is reported. Despite the employment of carbenoids as nucleophiles in reactions with carbon-centered electrophiles, sp(3)-type alkyl halides remain elusive materials fo...

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Detalles Bibliográficos
Autores principales: Miele, Margherita, Citarella, Andrea, Langer, Thierry, Urban, Ernst, Zehl, Martin, Holzer, Wolfgang, Ielo, Laura, Pace, Vittorio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8011987/
https://www.ncbi.nlm.nih.gov/pubmed/32910659
http://dx.doi.org/10.1021/acs.orglett.0c02831

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8011987/
https://www.ncbi.nlm.nih.gov/pubmed/32910659
http://dx.doi.org/10.1021/acs.orglett.0c02831

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