Unsupported Donor–Acceptor Complexes of Noble Gases with Group 13 Elements

[Image: see text] Unsupported donor–acceptor complexes of noble gases (Ng) with group 13 elements have been theoretically studied using density functional theory. Calculations reveal that heavier noble gases form thermodynamically stable compounds. The present study reveals that no rigid framework i...

Descripción completa

Detalles Bibliográficos
Autores principales: Mazumder, Lakhya J., Kalita, Amlan J., Rohman, Shahnaz S., Kashyap, Chayanika, Ullah, Sabnam S., Baruah, Indrani, Boro, Ashapurna, Guha, Ankur K., Sharma, Pankaz K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8015094/
https://www.ncbi.nlm.nih.gov/pubmed/33817527
http://dx.doi.org/10.1021/acsomega.1c00543
_version_ 1783673616246767616
author Mazumder, Lakhya J.
Kalita, Amlan J.
Rohman, Shahnaz S.
Kashyap, Chayanika
Ullah, Sabnam S.
Baruah, Indrani
Boro, Ashapurna
Guha, Ankur K.
Sharma, Pankaz K.
author_facet Mazumder, Lakhya J.
Kalita, Amlan J.
Rohman, Shahnaz S.
Kashyap, Chayanika
Ullah, Sabnam S.
Baruah, Indrani
Boro, Ashapurna
Guha, Ankur K.
Sharma, Pankaz K.
author_sort Mazumder, Lakhya J.
collection PubMed
description [Image: see text] Unsupported donor–acceptor complexes of noble gases (Ng) with group 13 elements have been theoretically studied using density functional theory. Calculations reveal that heavier noble gases form thermodynamically stable compounds. The present study reveals that no rigid framework is necessary to stabilize the donor–acceptor complexes. Rather, prepyramidalization at the Lewis acid center may be an interesting alternative to stabilize these complexes. Detailed bonding analyses reveal the formation of two-center–two-electron dative bonding, where Ng atoms act as a donor.
format Online
Article
Text
id pubmed-8015094
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-80150942021-04-02 Unsupported Donor–Acceptor Complexes of Noble Gases with Group 13 Elements Mazumder, Lakhya J. Kalita, Amlan J. Rohman, Shahnaz S. Kashyap, Chayanika Ullah, Sabnam S. Baruah, Indrani Boro, Ashapurna Guha, Ankur K. Sharma, Pankaz K. ACS Omega [Image: see text] Unsupported donor–acceptor complexes of noble gases (Ng) with group 13 elements have been theoretically studied using density functional theory. Calculations reveal that heavier noble gases form thermodynamically stable compounds. The present study reveals that no rigid framework is necessary to stabilize the donor–acceptor complexes. Rather, prepyramidalization at the Lewis acid center may be an interesting alternative to stabilize these complexes. Detailed bonding analyses reveal the formation of two-center–two-electron dative bonding, where Ng atoms act as a donor. American Chemical Society 2021-03-16 /pmc/articles/PMC8015094/ /pubmed/33817527 http://dx.doi.org/10.1021/acsomega.1c00543 Text en © 2021 The Authors. Published by American Chemical Society Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Mazumder, Lakhya J.
Kalita, Amlan J.
Rohman, Shahnaz S.
Kashyap, Chayanika
Ullah, Sabnam S.
Baruah, Indrani
Boro, Ashapurna
Guha, Ankur K.
Sharma, Pankaz K.
Unsupported Donor–Acceptor Complexes of Noble Gases with Group 13 Elements
title Unsupported Donor–Acceptor Complexes of Noble Gases with Group 13 Elements
title_full Unsupported Donor–Acceptor Complexes of Noble Gases with Group 13 Elements
title_fullStr Unsupported Donor–Acceptor Complexes of Noble Gases with Group 13 Elements
title_full_unstemmed Unsupported Donor–Acceptor Complexes of Noble Gases with Group 13 Elements
title_short Unsupported Donor–Acceptor Complexes of Noble Gases with Group 13 Elements
title_sort unsupported donor–acceptor complexes of noble gases with group 13 elements
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8015094/
https://www.ncbi.nlm.nih.gov/pubmed/33817527
http://dx.doi.org/10.1021/acsomega.1c00543
work_keys_str_mv AT mazumderlakhyaj unsupporteddonoracceptorcomplexesofnoblegaseswithgroup13elements
AT kalitaamlanj unsupporteddonoracceptorcomplexesofnoblegaseswithgroup13elements
AT rohmanshahnazs unsupporteddonoracceptorcomplexesofnoblegaseswithgroup13elements
AT kashyapchayanika unsupporteddonoracceptorcomplexesofnoblegaseswithgroup13elements
AT ullahsabnams unsupporteddonoracceptorcomplexesofnoblegaseswithgroup13elements
AT baruahindrani unsupporteddonoracceptorcomplexesofnoblegaseswithgroup13elements
AT boroashapurna unsupporteddonoracceptorcomplexesofnoblegaseswithgroup13elements
AT guhaankurk unsupporteddonoracceptorcomplexesofnoblegaseswithgroup13elements
AT sharmapankazk unsupporteddonoracceptorcomplexesofnoblegaseswithgroup13elements

Ejemplares similares