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Characterization of “Free Base” and Metal Complex Thioalkyl Porphyrazines by Magnetic Circular Dichroism and TDDFT Calculations
[Image: see text] UV–vis absorption and magnetic circular dichroism (MCD) spectra of octakis thioethyl “free base” porphyrazine H(2)OESPz and its metal complexes MOESPz (M = Mg, Zn, Ni, Pd, Cu), as well as of [MnOESPz(SH)] were recorded. In the last case, MCD proved to have quite good sensitivity to...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8016196/ https://www.ncbi.nlm.nih.gov/pubmed/33351631 http://dx.doi.org/10.1021/acs.jpcb.0c09277 |