Controlling Magnetic Anisotropy in a Zero-Dimensional S = 1 Magnet Using Isotropic Cation Substitution

[Image: see text] The [Zn(1–x)Ni(x)(HF(2))(pyz)(2)]SbF(6) (x = 0.2; pyz = pyrazine) solid solution exhibits a zero-field splitting (D) that is 22% larger [D = 16.2(2) K (11.3(2) cm(–1))] than that observed in the x = 1 material [D = 13.3(1) K (9.2(1) cm(–1))]. The substantial change in D is accompli...

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Detalles Bibliográficos
Autores principales: Manson, Jamie L., Curley, Samuel P. M., Williams, Robert C., Walker, David, Goddard, Paul A., Ozarowski, Andrew, Johnson, Roger D., Vibhakar, Anuradha M., Villa, Danielle Y., Rhodehouse, Melissa L., Birnbaum, Serena M., Singleton, John
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8017523/
https://www.ncbi.nlm.nih.gov/pubmed/33724822
http://dx.doi.org/10.1021/jacs.0c12516

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