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Isomerization and Fragmentation Reactions on the [C(2)SH(4)] Potential Energy Surface: The Metastable Thione S-Methylide Isomer

[Image: see text] Thione S-methylide, parent species of the thiocarbonyl ylide family, is a 1,3-dipolar species on the [C(2)SH(4)] potential energy surface, not so much studied as its isomers, thiirane, vinyl thiol, and thioacetaldehyde. The conrotatory ring-closure reaction toward thiirane was stud...

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Detalles Bibliográficos
Autores principales: Salta, Zoi, Segovia, Marc E., Katz, Aline, Tasinato, Nicola, Barone, Vincenzo, Ventura, Oscar N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8023414/
https://www.ncbi.nlm.nih.gov/pubmed/33501826
http://dx.doi.org/10.1021/acs.joc.0c02835

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