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Benzylic C−H acylation by cooperative NHC and photoredox catalysis

Methods that enable site selective acylation of sp(3) C-H bonds in complex organic molecules are not well explored, particularly if compared with analogous transformations of aromatic and vinylic sp(2) C-H bonds. We report herein a direct acylation of benzylic C-H bonds by merging N-heterocyclic car...

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Detalles Bibliográficos
Autores principales: Meng, Qing-Yuan, Lezius, Lena, Studer, Armido
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8024347/
https://www.ncbi.nlm.nih.gov/pubmed/33824304
http://dx.doi.org/10.1038/s41467-021-22292-z