Mechanical strength and flexibility in [Formula: see text] -4H borophene

Very recently, a novel phase of hydrogenated borophene, namely [Formula: see text] -4H, has been synthesized in a free-standing form. Unlike pure borophenes, this phase shows very good stability in the air environment and possesses semiconducting characteristics. Because of the interesting stiffness and flexibility of borophenes, herein, we systematically studied the mechanical properties of this novel hydrogenated phase. Our results show that the monolayer is stiffer (Y[Formula: see text] = [Formula: see text] 195 N/m) than group IV and V 2D materials and even than MoS[Formula: see text] , while it is softer than graphene. Moreover, similar to other phases of borophene, the inherent anisotropy of the pure monolayer increases with hydrogenation. The monolayer can bear biaxial, armchair, and zigzag strains up to 16, 10, and 14% with ideal strengths of approximately 14, 9, and 12 N/m, respectively. More interestingly, it can remain semiconductor under this range of tension. These outstanding results suggest that the [Formula: see text] -4H is a promising candidate for flexible nanoelectronics.