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Crystal structure and Hirshfeld surface analysis of a copper(II) complex containing 2-nitrobenzoate and tetramethylethylenediamine ligands
The reaction of copper(II) sulfatepentahydrate with 2-nitrobenzoic acid and N,N,N′,N′-tetramethylethylenediamine (TMEDA) in basic solution produces the complex bis(2-nitrobenzoato-κO)(N,N,N′,N′-tetramethylethylenediamine-κ(2) N,N′)copper(II), [Cu(C(7)H(4)NO(4))(2)(C(6)H(16)N(2))] or [Cu(2-n...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8025849/ https://www.ncbi.nlm.nih.gov/pubmed/33936767 http://dx.doi.org/10.1107/S2056989021002802 |
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author | Kansiz, Sevgi Qadir, Adnan M. Dege, Necmi Yongxin, Li Saif, Eiad |
author_facet | Kansiz, Sevgi Qadir, Adnan M. Dege, Necmi Yongxin, Li Saif, Eiad |
author_sort | Kansiz, Sevgi |
collection | PubMed |
description | The reaction of copper(II) sulfatepentahydrate with 2-nitrobenzoic acid and N,N,N′,N′-tetramethylethylenediamine (TMEDA) in basic solution produces the complex bis(2-nitrobenzoato-κO)(N,N,N′,N′-tetramethylethylenediamine-κ(2) N,N′)copper(II), [Cu(C(7)H(4)NO(4))(2)(C(6)H(16)N(2))] or [Cu(2-nitrobenzoate)(2)(tmeda)]. Each carboxylate group of the 2-nitrobenzoate ligand is coordinated by Cu(II) atom in a monodentate fashion and two TMEDA ligand nitrogen atoms are coordinate by the metal center, giving rise to a distorted square-planar coordination environment. In the crystal, metal complexes are linked by centrosymmetric C—H⋯O hydrogen bonds, forming ribbons via a R (2) (2)(10) ring motif. These ribbons are linked by further C—H⋯O hydrogen bonds, leading to two-dimensional hydrogen-bonded arrays parallel to the bc plane. Weak π–π stacking interactions provide additional stabilization of the crystal structure. Hirshfeld surface analysis, d(norm) and two-dimensional fingerprint plots were examined to verify the contributions of the different intermolecular contacts within the supramolecular structure. The major interactions of the complex are O⋯H/H⋯O (44.9%), H⋯H (34%) and C⋯H (14.5%). |
format | Online Article Text |
id | pubmed-8025849 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-80258492021-04-30 Crystal structure and Hirshfeld surface analysis of a copper(II) complex containing 2-nitrobenzoate and tetramethylethylenediamine ligands Kansiz, Sevgi Qadir, Adnan M. Dege, Necmi Yongxin, Li Saif, Eiad Acta Crystallogr E Crystallogr Commun Research Communications The reaction of copper(II) sulfatepentahydrate with 2-nitrobenzoic acid and N,N,N′,N′-tetramethylethylenediamine (TMEDA) in basic solution produces the complex bis(2-nitrobenzoato-κO)(N,N,N′,N′-tetramethylethylenediamine-κ(2) N,N′)copper(II), [Cu(C(7)H(4)NO(4))(2)(C(6)H(16)N(2))] or [Cu(2-nitrobenzoate)(2)(tmeda)]. Each carboxylate group of the 2-nitrobenzoate ligand is coordinated by Cu(II) atom in a monodentate fashion and two TMEDA ligand nitrogen atoms are coordinate by the metal center, giving rise to a distorted square-planar coordination environment. In the crystal, metal complexes are linked by centrosymmetric C—H⋯O hydrogen bonds, forming ribbons via a R (2) (2)(10) ring motif. These ribbons are linked by further C—H⋯O hydrogen bonds, leading to two-dimensional hydrogen-bonded arrays parallel to the bc plane. Weak π–π stacking interactions provide additional stabilization of the crystal structure. Hirshfeld surface analysis, d(norm) and two-dimensional fingerprint plots were examined to verify the contributions of the different intermolecular contacts within the supramolecular structure. The major interactions of the complex are O⋯H/H⋯O (44.9%), H⋯H (34%) and C⋯H (14.5%). International Union of Crystallography 2021-03-19 /pmc/articles/PMC8025849/ /pubmed/33936767 http://dx.doi.org/10.1107/S2056989021002802 Text en © Kansiz et al. 2021 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Kansiz, Sevgi Qadir, Adnan M. Dege, Necmi Yongxin, Li Saif, Eiad Crystal structure and Hirshfeld surface analysis of a copper(II) complex containing 2-nitrobenzoate and tetramethylethylenediamine ligands |
title | Crystal structure and Hirshfeld surface analysis of a copper(II) complex containing 2-nitrobenzoate and tetramethylethylenediamine ligands |
title_full | Crystal structure and Hirshfeld surface analysis of a copper(II) complex containing 2-nitrobenzoate and tetramethylethylenediamine ligands |
title_fullStr | Crystal structure and Hirshfeld surface analysis of a copper(II) complex containing 2-nitrobenzoate and tetramethylethylenediamine ligands |
title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of a copper(II) complex containing 2-nitrobenzoate and tetramethylethylenediamine ligands |
title_short | Crystal structure and Hirshfeld surface analysis of a copper(II) complex containing 2-nitrobenzoate and tetramethylethylenediamine ligands |
title_sort | crystal structure and hirshfeld surface analysis of a copper(ii) complex containing 2-nitrobenzoate and tetramethylethylenediamine ligands |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8025849/ https://www.ncbi.nlm.nih.gov/pubmed/33936767 http://dx.doi.org/10.1107/S2056989021002802 |
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