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Crystal structure of (E)-1-(3-benzyl-5-phenyl-1,3-thiazol-2-ylidene)-2-[(E)-1,2,3,4-tetrahydronaphthalen-1-ylidene]hydrazin-1-ium bromide
In the title molecular salt, C(26)H(24)N(3)S(+)·Br(−), the dihedral angles between the thiazole ring and its attached phenyl and benzoyl rings are 54.81 (7) and 85.51 (7)°, respectively. In the crystal, ion pairs are linked by C—H⋯Br and N—H⋯Br hydrogen bonds and are connected into helical chains...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8025854/ https://www.ncbi.nlm.nih.gov/pubmed/33936769 http://dx.doi.org/10.1107/S2056989021002863 |
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| author | Mohamed, Shaaban K. Elgarhy, Sahar M. I. Hassan, Alaa A. Demirtaş, Güneş Mague, Joel. T. Ramli, Youssef |
| author_facet | Mohamed, Shaaban K. Elgarhy, Sahar M. I. Hassan, Alaa A. Demirtaş, Güneş Mague, Joel. T. Ramli, Youssef |
| author_sort | Mohamed, Shaaban K. |
| collection | PubMed |
| description | In the title molecular salt, C(26)H(24)N(3)S(+)·Br(−), the dihedral angles between the thiazole ring and its attached phenyl and benzoyl rings are 54.81 (7) and 85.51 (7)°, respectively. In the crystal, ion pairs are linked by C—H⋯Br and N—H⋯Br hydrogen bonds and are connected into helical chains extending along the c-axis direction by weak, electrostatic S⋯Br(−) interactions. A Hirshfeld surface analysis was performed, which showed the dominant role of H⋯H contacts (51.3%). |
| format | Online Article Text |
| id | pubmed-8025854 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2021 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-80258542021-04-30 Crystal structure of (E)-1-(3-benzyl-5-phenyl-1,3-thiazol-2-ylidene)-2-[(E)-1,2,3,4-tetrahydronaphthalen-1-ylidene]hydrazin-1-ium bromide Mohamed, Shaaban K. Elgarhy, Sahar M. I. Hassan, Alaa A. Demirtaş, Güneş Mague, Joel. T. Ramli, Youssef Acta Crystallogr E Crystallogr Commun Research Communications In the title molecular salt, C(26)H(24)N(3)S(+)·Br(−), the dihedral angles between the thiazole ring and its attached phenyl and benzoyl rings are 54.81 (7) and 85.51 (7)°, respectively. In the crystal, ion pairs are linked by C—H⋯Br and N—H⋯Br hydrogen bonds and are connected into helical chains extending along the c-axis direction by weak, electrostatic S⋯Br(−) interactions. A Hirshfeld surface analysis was performed, which showed the dominant role of H⋯H contacts (51.3%). International Union of Crystallography 2021-03-23 /pmc/articles/PMC8025854/ /pubmed/33936769 http://dx.doi.org/10.1107/S2056989021002863 Text en © Mohamed et al. 2021 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
| spellingShingle | Research Communications Mohamed, Shaaban K. Elgarhy, Sahar M. I. Hassan, Alaa A. Demirtaş, Güneş Mague, Joel. T. Ramli, Youssef Crystal structure of (E)-1-(3-benzyl-5-phenyl-1,3-thiazol-2-ylidene)-2-[(E)-1,2,3,4-tetrahydronaphthalen-1-ylidene]hydrazin-1-ium bromide |
| title | Crystal structure of (E)-1-(3-benzyl-5-phenyl-1,3-thiazol-2-ylidene)-2-[(E)-1,2,3,4-tetrahydronaphthalen-1-ylidene]hydrazin-1-ium bromide |
| title_full | Crystal structure of (E)-1-(3-benzyl-5-phenyl-1,3-thiazol-2-ylidene)-2-[(E)-1,2,3,4-tetrahydronaphthalen-1-ylidene]hydrazin-1-ium bromide |
| title_fullStr | Crystal structure of (E)-1-(3-benzyl-5-phenyl-1,3-thiazol-2-ylidene)-2-[(E)-1,2,3,4-tetrahydronaphthalen-1-ylidene]hydrazin-1-ium bromide |
| title_full_unstemmed | Crystal structure of (E)-1-(3-benzyl-5-phenyl-1,3-thiazol-2-ylidene)-2-[(E)-1,2,3,4-tetrahydronaphthalen-1-ylidene]hydrazin-1-ium bromide |
| title_short | Crystal structure of (E)-1-(3-benzyl-5-phenyl-1,3-thiazol-2-ylidene)-2-[(E)-1,2,3,4-tetrahydronaphthalen-1-ylidene]hydrazin-1-ium bromide |
| title_sort | crystal structure of (e)-1-(3-benzyl-5-phenyl-1,3-thiazol-2-ylidene)-2-[(e)-1,2,3,4-tetrahydronaphthalen-1-ylidene]hydrazin-1-ium bromide |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8025854/ https://www.ncbi.nlm.nih.gov/pubmed/33936769 http://dx.doi.org/10.1107/S2056989021002863 |
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