Crystallographic characterization of (C(5)H(4)SiMe(3))(3)U(BH(4))

New syntheses have been developed for the synthesis of (borohydrido-κ(3) H)tris­[η(5)-(tri­methyl­sil­yl)cyclo­penta­dien­yl]uranium(IV), [U(BH(4))(C(8)H(13)Si)(3)] or Cp′(3)U(BH(4)) (Cp′ = C(5)H(4)SiMe(3)) and its structure has been determined by single-crystal X-ray crystallography. This compound...

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Autores principales: Windorff, Cory J., Cross, Justin N., Scott, Brian L., Kozimor, Stosh A., Evans, William J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8025856/
https://www.ncbi.nlm.nih.gov/pubmed/33936762
http://dx.doi.org/10.1107/S2056989021002425
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author Windorff, Cory J.
Cross, Justin N.
Scott, Brian L.
Kozimor, Stosh A.
Evans, William J.
author_facet Windorff, Cory J.
Cross, Justin N.
Scott, Brian L.
Kozimor, Stosh A.
Evans, William J.
author_sort Windorff, Cory J.
collection PubMed
description New syntheses have been developed for the synthesis of (borohydrido-κ(3) H)tris­[η(5)-(tri­methyl­sil­yl)cyclo­penta­dien­yl]uranium(IV), [U(BH(4))(C(8)H(13)Si)(3)] or Cp′(3)U(BH(4)) (Cp′ = C(5)H(4)SiMe(3)) and its structure has been determined by single-crystal X-ray crystallography. This compound crystallized in the space group P [Image: see text] and the structure features three η (5)-coordinated Cp′ rings and a κ (3)-coordinated (BH(4))(−) ligand.
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spelling pubmed-80258562021-04-30 Crystallographic characterization of (C(5)H(4)SiMe(3))(3)U(BH(4)) Windorff, Cory J. Cross, Justin N. Scott, Brian L. Kozimor, Stosh A. Evans, William J. Acta Crystallogr E Crystallogr Commun Research Communications New syntheses have been developed for the synthesis of (borohydrido-κ(3) H)tris­[η(5)-(tri­methyl­sil­yl)cyclo­penta­dien­yl]uranium(IV), [U(BH(4))(C(8)H(13)Si)(3)] or Cp′(3)U(BH(4)) (Cp′ = C(5)H(4)SiMe(3)) and its structure has been determined by single-crystal X-ray crystallography. This compound crystallized in the space group P [Image: see text] and the structure features three η (5)-coordinated Cp′ rings and a κ (3)-coordinated (BH(4))(−) ligand. International Union of Crystallography 2021-03-12 /pmc/articles/PMC8025856/ /pubmed/33936762 http://dx.doi.org/10.1107/S2056989021002425 Text en © Windorff et al. 2021 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Windorff, Cory J.
Cross, Justin N.
Scott, Brian L.
Kozimor, Stosh A.
Evans, William J.
Crystallographic characterization of (C(5)H(4)SiMe(3))(3)U(BH(4))
title Crystallographic characterization of (C(5)H(4)SiMe(3))(3)U(BH(4))
title_full Crystallographic characterization of (C(5)H(4)SiMe(3))(3)U(BH(4))
title_fullStr Crystallographic characterization of (C(5)H(4)SiMe(3))(3)U(BH(4))
title_full_unstemmed Crystallographic characterization of (C(5)H(4)SiMe(3))(3)U(BH(4))
title_short Crystallographic characterization of (C(5)H(4)SiMe(3))(3)U(BH(4))
title_sort crystallographic characterization of (c(5)h(4)sime(3))(3)u(bh(4))
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8025856/
https://www.ncbi.nlm.nih.gov/pubmed/33936762
http://dx.doi.org/10.1107/S2056989021002425
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