Cargando…

Crystallographic characterization of (C(5)H(4)SiMe(3))(3)U(BH(4))

New syntheses have been developed for the synthesis of (borohydrido-κ(3) H)tris[η(5)-(trimethylsilyl)cyclopentadienyl]uranium(IV), [U(BH(4))(C(8)H(13)Si)(3)] or Cp′(3)U(BH(4)) (Cp′ = C(5)H(4)SiMe(3)) and its structure has been determined by single-crystal X-ray crystallography. This compound...

Descripción completa

Detalles Bibliográficos
Autores principales:	Windorff, Cory J., Cross, Justin N., Scott, Brian L., Kozimor, Stosh A., Evans, William J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2021
Materias:	Research Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8025856/ https://www.ncbi.nlm.nih.gov/pubmed/33936762 http://dx.doi.org/10.1107/S2056989021002425

Ejemplares similares

Evaluating the electronic structure of formal Ln(II) ions in Ln(II)(C(5)H(4)SiMe(3))(3) (1–) using XANES spectroscopy and DFT calculations
por: Fieser, Megan E., et al.
Publicado: (2017)

Reactivity of the Bicyclic Amido‐Substituted Silicon(I) Ring Compound Si(4){N(SiMe(3))Mes}(4) with FLP‐Type Character
por: Schwedtmann, Kevin, et al.
Publicado: (2021)

Synthesis and electronic structure analysis of the actinide allenylidenes, [{(NR(2))(3)}An(CCCPh(2))](−) (An = U, Th; R = SiMe(3))
por: Kent, Greggory T., et al.
Publicado: (2021)

Quantitation of the THF Content in Fe[N(SiMe(3))(2)](2)·xTHF
por: Broere, Daniël L. J., et al.
Publicado: (2017)

[U(III){N(SiMe(2)tBu)(2)}(3)]: A Structurally Authenticated Trigonal Planar Actinide Complex
por: Goodwin, Conrad AP, et al.
Publicado: (2014)

Fast and scalable solvent-free access to Lappert's heavier tetrylenes E{N(SiMe(3))(2)}(2) (E = Ge, Sn, Pb) and ECl{N(SiMe(3))(2)} (E = Ge, Sn)
por: Cabeza, Javier A., et al.
Publicado: (2023)

Correction: Fast and scalable solvent-free access to Lappert's heavier tetrylenes E{N(SiMe(3))(2)}(2) (E = Ge, Sn, Pb) and ECl{N(SiMe(3))(2)} (E = Ge, Sn)
por: Cabeza, Javier A., et al.
Publicado: (2023)

Reduction of K(+) or Li(+) in the Heterobimetallic Electride K(+)[LiN(SiMe(3))(2)]e(–)
por: Davison, Nathan, et al.
Publicado: (2023)

Low‐Temperature Isolation of a Labile Silylated Hydrazinium‐yl Radical Cation, [(Me(3)Si)(2)N−N(H)SiMe(3)](.+)
por: Reiß, Fabian, et al.
Publicado: (2022)

Synthesis and Reduction of Bimetallic Methyl-Bridged Rare-Earth Metal Complexes, [(C(5)H(4)SiMe(3))(2)Ln(μ-CH(3))](2) (Ln = Y, Tb, Dy)
por: Dumas, Megan T., et al.
Publicado: (2019)

Properties of silicon dioxide layers with embedded metal nanocrystals produced by oxidation of Si:Me mixture
por: Novikau, Andrei, et al.
Publicado: (2011)

Dissociation of the Disilatricyclic Diallylic Dianion [(C(4)Ph(4)SiMe)(2)](−2) to the Silole Anion [MeSiC(4)Ph(4)](−) by Halide Ion Coordination or Halide Ion Nucleophilic Substitution at the Silicon Atom
por: Hong, Jang-Hwan
Publicado: (2011)

Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C(5)H(3)(SiMe(3))(2)](3)Th}(1–) anion containing thorium in the formal +2 oxidation state
por: Langeslay, Ryan R., et al.
Publicado: (2015)

Synthesis of an [(NHC)(2)Pd(SiMe(3))(2)] Complex and Catalytic cis-Bis(silyl)ations of Alkynes with Unactivated Disilanes**
por: Ansell, Melvyn B, et al.
Publicado: (2015)

Crystal structure of (tert-butyldimethylsilyl)triphenylgermane, Ph(3)Ge-SiMe(2)(t-Bu)
por: Zaitsev, Kirill V., et al.
Publicado: (2015)

Reactive Solubilization of Heterometallic Clusters by Treatment of (TrBi(3))(2−) Anions (Tr=Ga, In, Tl) with [Mn{N(SiMe(3))(2)}(2)]
por: Rienmüller, Julia, et al.
Publicado: (2022)

LiGe(SiMe(3))(3): A New Substituent for the Synthesis of Metalloid Tin Clusters from Metastable Sn(I) Halide Solutions
por: Binder, Mareike, et al.
Publicado: (2018)

Trans-Metal-Trapping Meets Frustrated-Lewis-Pair Chemistry: Ga(CH(2)SiMe(3))(3)-Induced C–H Functionalizations
por: Uzelac, Marina, et al.
Publicado: (2017)

David Sime
Publicado: (1916)

Merging Pincer Motifs and Potential Metal–Metal Cooperativity in Cobalt Dinitrogen Chemistry: Efficient Catalytic Silylation of N(2) to N(SiMe(3))(3)
por: Li, Ming, et al.
Publicado: (2021)

Imine Reduction with Me(2)S-BH(3)
por: Kamal, Mohammad M., et al.
Publicado: (2021)

Sodium mediated deprotonative borylation of arenes using sterically demanding B(CH(2)SiMe(3))(3): unlocking polybasic behaviour and competing lateral borane sodiation
por: Tortajada, Andreu, et al.
Publicado: (2023)

Trifluoromethylation of [AuF(3)(SIMes)]: Preparation and Characterization of [Au(CF(3))(x)F(3−x)(SIMes)] (x=1–3) Complexes
por: Winter, Marlon, et al.
Publicado: (2020)

John Sime Cowan
Publicado: (1880)

A beam destination read-out for BH3∕BH4
por: Tanke, E
Publicado: (1984)

Interface de controle de BH3 et BH4
por: Liénard, P
Publicado: (1984)

Solvent Impact on the Diversity of Products in the Reaction of Lithium Diphenylphosphide and a Ti(III) Complex Supported by a tBu(2)P–P(SiMe(3)) Ligand
por: Ziółkowska, A., et al.
Publicado: (2020)

Synthesis and NMR-Study of 1-Trimethylsilyl Substituted Silole Anion [Ph(4)C(4)Si(SiMe(3))](−)•[Li](+) and 3-Silolenide 2,5-carbodianions {[Ph(4)C(4)Si(n-Bu)(2)](−2)•2[Li](+), [Ph(4)C(4)Si(t-Bu)(2)](−2)•2[Li](+)} via Silole Dianion [Ph(4)C(4)Si](−2)•2[Li](+)
por: Hong, Jang-Hwan
Publicado: (2013)

Structural and electronic properties of KY(BH(4))(4): DFT+U study
por: Liu, Chuan, et al.
Publicado: (2018)

Activation of SF(5)CF(3) by the N-Heterocyclic Carbene SIMes
por: Herbstritt, Domenique, et al.
Publicado: (2023)

High pressure polymorphism of LiBH(4) and of NaBH(4)
por: Marizy, Adrien, et al.
Publicado: (2021)

Impact of Visual Impairment and Eye diseases on Mortality: the Singapore Malay Eye Study (SiMES)
por: Siantar, Rosalynn Grace, et al.
Publicado: (2015)

Crystal structure of the inverse crown ether tetrakis[μ(2)-bis(trimethylsilyl)amido]-μ(4)-oxido-dicobalt(II)disodium, [Co(2)Na(2){μ(2)-N(SiMe(3))(2)}(4)](μ(4)-O)
por: Hansen, Christopher B., et al.
Publicado: (2016)

Phylogenetic analysis of the MCL1 BH3 binding groove and rBH3 sequence motifs in the p53 and INK4 protein families
por: McGriff, Anna, et al.
Publicado: (2023)

Role of BH3-only protein Bim in autoimmune and degenerative diseases
por: Bouillet, P, et al.
Publicado: (2003)

Proyecto SIME en comisión federal de electricidad /
por: Gutierrez Vazquez, Ma. Guadalupe
Publicado: (2000)

SIMED-new doc course, a matter of reflection
por: Stirparo, Giuseppe, et al.
Publicado: (2023)

The structure of kaliophilite KAlSiO(4), a long-lasting crystallographic problem
por: Mugnaioli, Enrico, et al.
Publicado: (2020)

Reduction of the Diazo Functionality of α-Diazocarbonyl Compounds into a Methylene Group by NH(3)BH(3) or NaBH(4) Catalyzed by Au Nanoparticles
por: Kidonakis, Marios, et al.
Publicado: (2021)

Useful Method for the Preparation of Low-Coordinate Nickel(I) Complexes via Transformations of the Ni(I) Bis(amido) Complex K{Ni[N(SiMe(3))(2,6-(i)Pr(2)-C(6)H(3))](2)}
por: Lipschutz, Michael I., et al.
Publicado: (2014)

Cannot write session to /tmp/vufind_sessions/sess_oklbsug9ubrevk8e460ckqj1jg